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铅硼硅酸盐玻璃中Al2O3含量对复相玻璃陶瓷性能的影响
引用本文:邵辉,周洪庆,朱海奎,沈晓冬.铅硼硅酸盐玻璃中Al2O3含量对复相玻璃陶瓷性能的影响[J].南京工业大学学报(自然科学版),2011,33(3):6-10.
作者姓名:邵辉  周洪庆  朱海奎  沈晓冬
作者单位:南京工业大学,材料科学与工程学院,江苏南京210009
基金项目:国家高技术研究发展计划(863计划)资助项目
摘    要:以低软化点的铅硼硅酸盐玻璃和Al2O3粉末为原料,制备Al2O3/玻璃低温共烧复合玻璃陶瓷材料。考察烧结温度和添加不同质量分数的Al2O3对复合玻璃陶瓷烧结机制和微波介电性能的影响,并探讨了作用机制。结果表明:Al2O3掺入PbO-B2O3-SiO2玻璃中改善了与Al2O3陶瓷的界面润湿,对烧结有一定的促进作用。在添加质量分数为4%Al2O3的复相玻璃陶瓷、烧成温度为850℃时性能最好,其密度为3.1 g/cm3,介电常数为8.46,介电损耗为0.001 1。

关 键 词:低温共烧陶瓷  Al2O3  烧结机制  介电性能

Effects of mass fraction of Al2O3 on properties of PbO-B2O3-SiO2 glass-ceramics
SHAO Hui,ZHOU Hongqing,ZHU Haikui,SHEN Xiaodong.Effects of mass fraction of Al2O3 on properties of PbO-B2O3-SiO2 glass-ceramics[J].Journal of Nanjing University of Technology,2011,33(3):6-10.
Authors:SHAO Hui  ZHOU Hongqing  ZHU Haikui  SHEN Xiaodong
Institution:(College of Materials Science and Engineering,Nanjing University of Technology,Nanjing 210009,China)
Abstract:The low temperature sintering composite material of Al2O3/glass was prepared with low softening temperature PbO-B2O3-SiO2 glass and Al2O3 powder as raw materials.Sintering and dielectric properties of Al2O3 doped glass-ceramics were discussed.It was found that sintering process of glass-ceramics was promoted by using Al2O3 additives because of the excellent wetting behavior between the alumina and the PbO-B2O3-SiO2 glass liquid phases.When 4% Al2O3 was added and sintered at 850 ℃,glass-ceramics exhibited good dielectric properties at ρ=3.1 g/cm3,εr=8.46,tanδ=0.001 1.
Keywords:LTCC  alumina  sintering mechanism  dielectric properties
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