| 薄层光谱电化学的研究 |
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| 引用本文： | 朱元保,谢青季.薄层光谱电化学的研究[J].湖南大学学报(自然科学版),1991,18(2):112-117. |
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| 作者姓名： | 朱元保 谢青季 |
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| 作者单位： | 湖南大学化学化工系
(朱元保，谢青季)，湖南大学化学化工系(周名成) |
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| 摘 要： |
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| 关 键 词： | 光谱电化学 光谱电化学池 薄层 |
Studies of the Thin-Layer Spectroelectrochemistry |
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| Zhu Yuanbao Xie Qingji Zhou Mingcheng.Studies of the Thin-Layer Spectroelectrochemistry[J].Journal of Hunan University(Naturnal Science),1991,18(2):112-117. |
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| Authors: | Zhu Yuanbao Xie Qingji Zhou Mingcheng |
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| Institution: | Department of Chemistry and Chemical Engineering |
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| Abstract: | The formal potentials and the numbers of electron transferred of the redox systems of Fe(CN)_6~(3-)/Fe(CN)_6~(4-) and methylene blue were determined with a Long-Path Length Thin-Layer spectroelectrochemical cell. The results obtained from our experiments were in good agreement with the reported values and those obtained from CV experiments. This paper also gave a simple equation of absorbance-time behavior when the redox system investigated with a Long-Path Length Thin-Layer spectroelectrehemical cell is controlled by diffusion. The diffusion coeffients of the reacting substances were obtained from this equation. |
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| Keywords: | s diffusion coefficient electrochemistry spectroscopy/long-path length thin-layer spectroelectrochemical cell |
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