| 含乙烯基基团的聚硅烷的合成与表征 |
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| 引用本文： | 熊远钦,倪宇,于江,张正华,卢彦兵,徐伟箭.含乙烯基基团的聚硅烷的合成与表征[J].湖南大学学报(自然科学版),2007,34(10):82-85. |
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| 作者姓名： | 熊远钦 倪宇 于江 张正华 卢彦兵 徐伟箭 |
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| 作者单位： | 湖南大学,化学化工学院,湖南,长沙,410082 |
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| 基金项目： | 湖南大学化学/生物传感和计量学国家重点实验室开放基金 |
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| 摘 要： | 以甲基乙烯基二氯硅烷为单体,采用超声钠缩合法合成聚(甲基-乙烯基)硅烷;在此基础上,采用相同的方法,变化单体以甲基乙烯基二氯硅烷和甲基苯基二氯硅烷为原料,合成了共聚硅烷和有一定程度交联的聚甲基乙烯基硅烷,并对它们用FT-IR,1HNMR,UV,TGA进行了表征.结果表明,聚(甲基-乙烯基)硅烷产物产率从2%提高到了28%;各种产物聚硅烷中均含有大量乙烯基基团,有利于进一步进行其他官能化反应.
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| 关 键 词： | 聚硅烷 超声合成法 甲基乙烯基二氯硅烷 共聚物 |
| 文章编号： | 1000-2472（2007）10-0082-04 |
| 修稿时间： | 2007-04-10 |
Synthesis and Characterization of Polysilane with Vinyl |
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| XIONG Yuan-qin,NI Yu,YU Jiang,ZHANG zheng-hu,LU Yan-bing,XU Wei-jian.Synthesis and Characterization of Polysilane with Vinyl[J].Journal of Hunan University(Naturnal Science),2007,34(10):82-85. |
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| Authors: | XIONG Yuan-qin NI Yu YU Jiang ZHANG zheng-hu LU Yan-bing XU Wei-jian |
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| Institution: | College of Chemistry and Chemical Engineering, Hunan Univ, Changsha, Hunan 410082, China |
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| Abstract: | Polymethylvinylsilane was synthesized in the ultrsonic coupling method using dichloromethylvinylsilane as the monomers.The poly(methlvinylsilane-co-methylphenylsilane) and the cross-linked polymethylvinylsilane were synthesized in the same method.They were characterized by FT-IR,1HNMR,UV and TGA.The results showed that the yield of polymethylvinylsilane rose from 2% to 28%,and the polysilanes contained vinyl,which was capable of being further functionalized. |
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| Keywords: | polysilanes ultrasonic dichloromethylvinylsilane copolymer |
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