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库仑法测定微量铜
引用本文:林文如,施联玉,许荣榕.库仑法测定微量铜[J].福州大学学报(自然科学版),1987(2):107-110.
作者姓名:林文如  施联玉  许荣榕
作者单位:福州大学化学系 (林文如,施联玉),福州大学化学系(许荣榕)
摘    要:本文提出在HAc—NaAc介质中Cu3+与I-、SCN-反应生成I2,然后加入过量的Na2S2O3还 原I2,最后用电生I2回滴定过量的Na2S2O2。实验表明,用这种方法测定铜可行的,检测量可达 10-7数量级.

关 键 词:库仑法  测定铜

Determination of Micro-copper by Coulometric Method
Lin Wenru,Shi Lianyu and Xu Rongrong.Determination of Micro-copper by Coulometric Method[J].Journal of Fuzhou University(Natural Science Edition),1987(2):107-110.
Authors:Lin Wenru  Shi Lianyu and Xu Rongrong
Institution:Department of Chemistry
Abstract:It is put forth in this article that. in medium HAc-NaAc, let Cu 2+ react with I-, and SCN- to produce I2. then over-much Na2S2O3 was added to reduces I2, and lastly titration of the over-much Na2S2O2 with eletrogenerated I2 wa made again Experiments manifest that this method is feasible for determining copper, with the determination being in the order of magnitude of 10-7g.
Keywords:coulometric method  determination of micro-copper
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