| 4f~2组态离子能级探讨 |
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| 引用本文： | 周武树.4f~2组态离子能级探讨[J].四川师范大学学报(自然科学版),1989(4). |
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| 作者姓名： | 周武树 |
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| 作者单位： | 四川师范大学化学系 |
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| 摘 要： | 本文采用中间场耦合方法计算了组态为4f~2的Pr~(3 ),Nd~(4 )离子能级(计算值与实验值吻合较好),得出了二组自由离子能级参量。在此基础上讨论了自由离子能级(含有自由离子能级参量)与离子实有效核电荷的关系。
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| 关 键 词： | 中间场耦合 自由离子能级 离子实有效核电荷 |
a Study of Energy Levels on the Ions With 4f~2 Configuratiou |
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| Zhou Wushu.a Study of Energy Levels on the Ions With 4f~2 Configuratiou[J].Journal of Sichuan Normal University(Natural Science),1989(4). |
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| Authors: | Zhou Wushu |
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| Institution: | Department of Chemistry |
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| Abstract: | By means of intermediate-field coupling,the energy levels of Pr~(3 ),Nd~(4 )ions with 4f~2configuration are calculated(there is a good agreement between ealculatid and experimentvalue)and two groups free-ion Parameters are obtained.On the tbasis of these,the relationbetween the free-ion energy levels(containing free ion parameters)and ion core effectivenuclear charge are discussed. |
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| Keywords: | Intermediate coupling free ion energy level ion core effective nuclear charge |
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