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电沉积壳聚糖-镝复合涂层缓蚀性的研究
引用本文:陈敏,肖亚平,杜涛,任乔林,覃彩芹,李伟.电沉积壳聚糖-镝复合涂层缓蚀性的研究[J].孝感师专学报,2013(6):20-23.
作者姓名:陈敏  肖亚平  杜涛  任乔林  覃彩芹  李伟
作者单位:[1]孝感供电公司检修公司,湖北孝感432000 [2]湖北工程学院,湖北孝感432000
基金项目:湖北省电力公司2013年科技项目(2001)
摘    要:以壳聚糖和镝为原料,利用电沉积技术在铜片上形成新型的壳聚糖-镝复合涂层.涂层的耐腐蚀性采用电子扫描显微镜(SEM)、X射线能谱(EDS)、动电位极化测量(TAFEL曲线)和电化学交流阻抗(EIS)进行研究.试验结果表明,在电压为5V,沉积时间为5min,溶液pH=3.8的室温条件下可以在铜表面形成稳定、均匀的壳聚糖-镝复合涂层,该涂层能够显著提高铜片在酸性体系中的缓蚀性.

关 键 词:壳聚糖    电沉积

Study of Stability and Corrosion Inhibition of Electrophoretic Deposited Chitosan-dysprosium on Copper
Chen Min Xiao Yaping Du Tao Ren Qiaolin Qin Caiqin Li Wei.Study of Stability and Corrosion Inhibition of Electrophoretic Deposited Chitosan-dysprosium on Copper[J].Journal of Xiaogan University,2013(6):20-23.
Authors:Chen Min Xiao Yaping Du Tao Ren Qiaolin Qin Caiqin Li Wei
Institution:Chen Min Xiao Yaping Du Tao Ren Qiaolin Qin Caiqin Li Wei (1. Maintenance Company of Xiaogan Power Supply, Xiaogan, Hubei 432000, China ; 2. School of Chemistry and Material Science, Hubei Engineering University ,Xiaogan, Hubei 432000, China)
Abstract:The electrophoretic deposition (EPD) of chitosan (CS) and dysprosium on copper substrates was done in the experiment. The stability and corrosion inhibition of the new kind of chitosan-dyspro- sium coating on copper was investigated by scanning electron microscopy (SEM), energy dispersion spectrum(EDS), potentiodynamic polarization measurements (TAFEL), and electrochemical imped- ance spectroscopy (EIS). Results indicated that stable and uniform coating on copper surface could be formed at the voltage of 5V, the deposition time of 5min, solution pH=3.8 and room temperature. The coating could significantly improve the corrosion inhibition of copper in scid system.
Keywords:chitosan  dysprosium  electrodeposition
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