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| 形变医用镍钛合金表面TiN涂层耐蚀性的研究 | |
| 引用本文： | 曾卫军,陈智琴,张德元.形变医用镍钛合金表面TiN涂层耐蚀性的研究[J].江西科学,2009,27(5):670-674. |
| 作者姓名： | 曾卫军 陈智琴 张德元 |
| 作者单位： | 1. 江西省科学院应用物理研究所,江西,南昌,330029 2. 江西科技师范学院材料科学与工程学院,江西,南昌,330013 3. 先健科技(深圳)有限公司,广东,深圳,518000 |
| 摘 要： | 在37℃的人造血浆中,研究了有无TiN涂覆层的镍钛合金的耐蚀性。电化学实验显示TiN涂层能使其相对饱和甘汞电极的电位从0.95 V增至1.5 V,其腐蚀电流密度从0.20 mA/cm2降至0.10 mA/cm2。溶解的钛离子和镍离子的化合价为正二价。变形量小于6%时,镍钛基TiN膜层的耐蚀性并未受到严重影响。由于变形产生的TiN膜层裂纹而导致了轻微的腐蚀,但其耐蚀性仍好于没有TiN膜层的镍钛合金,因为在裂纹处未观察到电偶腐蚀。 |
| 关 键 词： | 氮化钛 镍钛合金 耐蚀性 |
Study on Corrosion Resistance of TiN Coated Biomedical Nitinol under Deformation |
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| Institution: | ZENG Wei-jun,CHEN Zhi-qin,ZHANG De-yuan (1. Institute of Applied Physics,Jiangxi Academy of Sciences, Jiangxi Nanchang 330029 PRC; 2. College of Materials Science and Engineering,Jiangxi Science and Technology Normal University, Jiangxi Nanchang 330013 PRC ; 3. Lifetech Scientific (Shenzhen) Co. ,Ltd, Guangdong Shenzhen 518000 PRC) |
| Abstract: | The corrosion resistance of nitinol with and without a titanium nitride coating is electrochemically investigated at 37 ℃ in artificial plasma. The electrochemical experiments show that the titanium nitride （TiN） coating can increase the stable potential from 0.95 V to 1.5 V versus a saturated calomel electrode and reduce the corrosion current density from 0.20 mA/cm^2 to 0. 10 mA/ cm^2. The valence of the dissolved titanium and nickel ions is plus two. At deformation less than 6%, no significant negative effects on the corrosion resistance of the TiN coated nitinol is observed. More deformation causes cracks in the TiN coatings and consequently, the corrosion resistance degrades slightly, but it is still better than that of the uncoated nitinol since no galvanic corrosion is observed from the broken areas. |
| Keywords: | Titanium nitride Nitinol Corrosion resistance |
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