| 铁催化烯基环丙烷类化合物的三氟甲基化反应 |
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| 引用本文： | 李宗瑞,邓清海.铁催化烯基环丙烷类化合物的三氟甲基化反应[J].上海师范大学学报(自然科学版),2016,45(6):655-662. |
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| 作者姓名： | 李宗瑞 邓清海 |
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| 作者单位： | 上海师范大学,上海师范大学 |
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| 基金项目： | 国家自然科学基金(21402119);上海高校特聘教授 (东方学者) 岗位计划资助;上海市青年科技启明星计划(16QA1403100) |
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| 摘 要： | 对铁催化的烯基环丙烷类化合物的自由基三氟甲基化反应进行了研究.以中等到良好的收率获得了含三氟甲基的二氢萘衍生物.方法具有反应条件温和,催化剂廉价易得,反应时间短等优点.同时对反应机理进行了初步研究.
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| 关 键 词： | 铁催化 三氟甲基化 自由基反应 二氢萘 |
| 收稿时间： | 2016/9/22 0:00:00 |
Iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes |
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| LI Zongrui and DENG Qinghai.Iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes[J].Journal of Shanghai Normal University(Natural Sciences),2016,45(6):655-662. |
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| Authors: | LI Zongrui and DENG Qinghai |
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| Institution: | College of Life and Environmental Sciences,Shanghai Normal University and College of Life and Environmental Sciences,Shanghai Normal University |
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| Abstract: | An efficient iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes was developed.A series of CF3-containing dihydronaphthalene derivatives were prepared with a moderate to high yield.This method offers several advantages in terms of its mild condition,readily available and cheap catalyst,as well as short reaction time.Furthermore,the reaction mechanism was investigated preliminarily. |
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| Keywords: | iron(II)-catalyzed trifluoromethylation radical reaction dihydronaphthalene |
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