| Salen-Co(Ⅲ)配合物催化CO_2和环氧乙烷生成环状碳酸酯 |
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| 引用本文： | 王益,陈冕,刘杰.Salen-Co(Ⅲ)配合物催化CO_2和环氧乙烷生成环状碳酸酯[J].云南民族大学学报(自然科学版),2014,23(5):331-336. |
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| 作者姓名： | 王益 陈冕 刘杰 |
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| 作者单位： | 云南师范大学化学与分子工程学院,云南昆明,650500 |
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| 基金项目： | 国家自然科学基金，云南省教育厅科学研究基金 |
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| 摘 要： | Salen-Co(Ⅲ)配合物催化CO2和环氧化合物合成环状碳酸酯的反使用了温室气体CO2为原料来合成有用的分子,同时该反应符合原子经济性,是最有潜力的绿色化学反应之一.讨论了Salen-Co(Ⅲ)配合物催化CO2和环氧化合物合成环状碳酸酯反应中取得的重大进展,尤其是催化合成手性环状碳酸酯的化学选择性问题.
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| 关 键 词： | Salen-Co(Ⅲ)配合物 二氧化碳 环状碳酸酯 反应选择性 |
Salen-Co(Ⅲ) complexes mediated formation of cyclic carbonates by cycloaddition of CO2 to epoxides |
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| WANG Yi,CHEN Mian,LIU Jie.Salen-Co(Ⅲ) complexes mediated formation of cyclic carbonates by cycloaddition of CO2 to epoxides[J].Journal of Yunnan Nationalities University:Natural Sciences Edition,2014,23(5):331-336. |
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| Authors: | WANG Yi CHEN Mian LIU Jie |
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| Institution: | WANG Yi;CHEN Mian;LIU Jie;School of Chemistry and Chemical Engineering,Yunnan Normal University; |
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| Abstract: | Salen- Co( Ⅲ) complexes that catalyze the formation of cyclic carbonates by cycloaddition of CO2 and epoxides used the greenhouse gas as the raw material to synthesize useful molecules,meanwhile,the reaction is consistent with atomiceconomy and it is one of the most promising green processes. This paper discusses the significant progress of the formation of cyclic carbonates by cycloaddition of CO2 to epoxides catalyzed by Salen- Co( Ⅲ) complexes. In particular,the chemical selectivity of catalytic synthesis of chiral cyclic carbonate is also discussed. |
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| Keywords: | Salen-Co (Ⅲ) complexes carbon dioxide cyclic carbonates reaction selectivity |
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