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O'-Sialon/BN和O'-Sialon/ZrO2复合材料抗熔融金属和保护渣侵蚀
引用本文:包宏,甄强,李文超.O'-Sialon/BN和O'-Sialon/ZrO2复合材料抗熔融金属和保护渣侵蚀[J].北京科技大学学报,2001,23(4):311-315.
作者姓名:包宏  甄强  李文超
作者单位:北京科技大学冶金学院
基金项目:国家自然科学基金;59872002,59874006;
摘    要:研究了O′-Sialon/BN和O′-Sialon/ZrO2复合材料抗溶融金属和保护渣侵蚀,结果表明:O′-Sialon/BN复合材料抗钢水侵蚀的动力学分为两段控制:前期为界面化学反应控制,后期为扩散控制,O′-Sialon/ZrO2复合材料具有良好的保护渣侵蚀性能,这是由于ZrO2在硅酸盐溶体中的溶解度较低,随着ZrO2的增加,抑制了O′-Sialon与CO,以及渣中其他组元的反应,从而提高了O′-Sialon抗的侵蚀性。

关 键 词:分形  复合材料  连铸  保护渣  耐火材料  熔融金属  侵蚀
修稿时间:2000年12月1日

Anti-Errosion of O'-Sialon/BN and O'-Sialon/ZrO2 Composites in Molten Steel and Slag
BAOHong,ZHENQang,LI Wechao Metallurgy School,UST Beijing,Beijing ,CHina , City Key Laboratony of Iron and Steel Metallurgy Shanghai ,China.Anti-Errosion of O'-Sialon/BN and O'-Sialon/ZrO2 Composites in Molten Steel and Slag[J].Journal of University of Science and Technology Beijing,2001,23(4):311-315.
Authors:BAOHong  ZHENQang  LI Wechao Metallurgy School  UST Beijing  Beijing  CHina  City Key Laboratony of Iron and Steel Metallurgy Shanghai  China
Institution:BAOHong,ZHENQang,LI Wechao Metallurgy School,UST Beijing,Beijing 100083,CHina , City Key Laboratony of Iron and Steel Metallurgy Shanghai 200072,China
Abstract:Erosions of O'-Sialon/BN in molten Steel and O'-Sialon/ZrO2 in protective slag of continuous casting were investigated. According to eperimental results and theoretical analysis, erosion kinetics of the O'-Sialon/BN in molten steel was controlled by tWo steps: the first one is controlled by a chemical reaction taking place on the interface; the second one is controlled by diffusion through boundary layers. The O'- Sialon/ZrO2 composites had good erosion resistance to continuous casting protective slag because the solubility of ZrO2 in silicate melt is limited and the increment of ZrO2 content will prevent O'-Sialon from reacting with dissolved CO and other components in slag.
Keywords:O'-Sialon/BN  O'-Sialon/ZrO_2  erosion resistance  fractal  composite materials
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