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超临界氧化技术处理吐氏酸生产废水
引用本文:孙春宝,张嫔婕,李晨,俞洋.超临界氧化技术处理吐氏酸生产废水[J].北京科技大学学报,2012,34(10):1097-1101.
作者姓名:孙春宝  张嫔婕  李晨  俞洋
作者单位:1. 北京科技大学金属矿山高效开采与安全教育部重点实验室,北京,100083
2. 国电铜陵发电有限公司,铜陵,244153
摘    要:为更好地处理难降解的高浓度有机废水,研究了在间歇式超临界水反应装置内,超临界水氧化技术处理吐氏酸生产废水的最佳条件及其处理效果.通过单因素试验和正交试验,系统地研究了不同条件下废水COD和色度的去除率.当温度为380℃、压力为24 MPa、时间为150 s以及过氧比为1.8倍时,COD去除率可达96.7%,色度去除率可达97.5%,且反应后废水的可生化性有极大改善.

关 键 词:废水处理  吐氏酸  超临界水氧化  化学需氧量(COD)

Treatment of wastewater from Tobias acid production with supercritical water oxidation
SUN Chun-bao,ZHANG Pin-jie,LI Chen,YU Yang.Treatment of wastewater from Tobias acid production with supercritical water oxidation[J].Journal of University of Science and Technology Beijing,2012,34(10):1097-1101.
Authors:SUN Chun-bao  ZHANG Pin-jie  LI Chen  YU Yang
Institution:1) Key Laboratory of the Ministry of Education of China for High-Efficient Mining and Safety of Metal Mines,University of Science and Technology Beijing,Beijing 100083,China 2) Guodian Tongling Power Generation Co.Ltd.,Tongling 244153,China
Abstract:In order to better treat high-concentration refractory organic wastewater,the optimum conditions and treatment effect for treating wastewater from Tobias acid production were studied in a batch-type supercritical water oxidation(SCWO) device by SCWO technology.Through single factor and orthogonal tests,the removal rates of COD and chrominance were investigated under different experimental conditions.When the temperature is 380 ℃,the pressure is 24 MPa,the residence time is 150s and the excess oxygen rate is 1.8,the removal rates of COD and chrominance reaches 96.7% and 97.5%,respectively,and the biodegradability of the wastewater is improved greatly.
Keywords:wastewater treatment  Tobias acid  supercritical water oxidation  chemical oxygen demand(COD)
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