象胶“热缩冷胀”的实验研究及其热力学分析 |
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引用本文: | 毛俊雯,罗骏,徐燕,许丹丹,任文英.象胶“热缩冷胀”的实验研究及其热力学分析[J].湖州师专学报,2014(2):23-26. |
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作者姓名: | 毛俊雯 罗骏 徐燕 许丹丹 任文英 |
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作者单位: | 湖州师范学院理学院,浙江湖州313000 |
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基金项目: | 国家自然科学基金(10947012). |
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摘 要: | 实验研究了恒定外力下橡皮圈伸长和温度的关系,并通过热力学分析发现橡胶的“热缩冷胀”正是熵弹性的体现.利用这一实验结果和热力学循环关系,得到了橡皮圈内能贡献和张力比值fe/f大约为20%.
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关 键 词: | 热缩冷胀 熵弹性 内能贡献 |
Experimental Investigation and Thermodynamic Analysis of Thermal Contraction of Rubber |
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Authors: | MAO Junwen LUO Jun XU Yan XU Dandan REN Wenying |
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Institution: | (School of Science, Journal of Huzhou University, Huzhou 313000, China) |
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Abstract: | High elasticity is a special mechanic property of rubber. Extended rubber contracts when being heated. We experimentally demonstrate this phenomenon and obtain the extension as a function ot temperature at different tensile forces. Through thermodynamic analysis, we find the abnormal expan- sion and contraction of rubber resulting from entropy elasticity. Further, we show the ratio of internal energy contribution and force fe/f is around 20% by virtue of our experimental results and thermody- namic cyclic relation. |
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Keywords: | Key words:contract when being heated and extend when being cooled entropy elasticity internal energycontribution |
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