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象胶“热缩冷胀”的实验研究及其热力学分析
引用本文:毛俊雯,罗骏,徐燕,许丹丹,任文英.象胶“热缩冷胀”的实验研究及其热力学分析[J].湖州师专学报,2014(2):23-26.
作者姓名:毛俊雯  罗骏  徐燕  许丹丹  任文英
作者单位:湖州师范学院理学院,浙江湖州313000
基金项目:国家自然科学基金(10947012).
摘    要:实验研究了恒定外力下橡皮圈伸长和温度的关系,并通过热力学分析发现橡胶的“热缩冷胀”正是熵弹性的体现.利用这一实验结果和热力学循环关系,得到了橡皮圈内能贡献和张力比值fe/f大约为20%.

关 键 词:热缩冷胀  熵弹性  内能贡献

Experimental Investigation and Thermodynamic Analysis of Thermal Contraction of Rubber
Authors:MAO Junwen  LUO Jun  XU Yan  XU Dandan  REN Wenying
Institution:(School of Science, Journal of Huzhou University, Huzhou 313000, China)
Abstract:High elasticity is a special mechanic property of rubber. Extended rubber contracts when being heated. We experimentally demonstrate this phenomenon and obtain the extension as a function ot temperature at different tensile forces. Through thermodynamic analysis, we find the abnormal expan- sion and contraction of rubber resulting from entropy elasticity. Further, we show the ratio of internal energy contribution and force fe/f is around 20% by virtue of our experimental results and thermody- namic cyclic relation.
Keywords:Key words:contract when being heated and extend when being cooled  entropy elasticity  internal energycontribution
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