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十六烷基三甲基溴化铵在不同酸介质中对冷轧钢腐蚀行为影响的研究
引用本文:李学铭,唐丽斌,张瑾,木冠南,刘光恒.十六烷基三甲基溴化铵在不同酸介质中对冷轧钢腐蚀行为影响的研究[J].云南大学学报(自然科学版),2002,24(2):157-160.
作者姓名:李学铭  唐丽斌  张瑾  木冠南  刘光恒
作者单位:云南大学化学系,云南,昆明,650091
基金项目:云南省应用基础研究基金资助项目 ( 2 0 0 0E0 0 17M )
摘    要: 用失重法研究了冷轧钢在不同浓度十六烷基三甲基溴化铵的盐酸、草酸、硝酸介质中的腐蚀行为,所得结果表明在盐酸介质中十六烷基三甲基溴化铵是冷轧钢优异的缓蚀剂,其在冷轧钢表面的吸附符合Langmuir模型,实验数据亦表明草酸溶液中十六烷基三甲基溴化铵对冷轧钢的腐蚀影响甚微,并且发现十六烷基三甲基溴化铵在硝酸介质中是冷轧钢腐蚀的增蚀剂.

关 键 词:冷轧钢  十六烷基三甲基溴化铵  盐酸  草酸  硝酸  缓蚀作用  腐蚀行为
文章编号:0258-7971(2002)02-0157-04
修稿时间:2001年9月8日

The Study of the Effect of Hexadecyltrimethylammonium Bromide on Cold Rolled Steel Corrosion in Various Acidic Media
LI Xue-ming,TANG Li-bin,ZHANG Jin,MU Guan-nan,LIU Guang-heng.The Study of the Effect of Hexadecyltrimethylammonium Bromide on Cold Rolled Steel Corrosion in Various Acidic Media[J].Journal of Yunnan University(Natural Sciences),2002,24(2):157-160.
Authors:LI Xue-ming  TANG Li-bin  ZHANG Jin  MU Guan-nan  LIU Guang-heng
Institution:Department of Chemistry, Yunnan University, Kunming 650091, China
Abstract:The corrosion behavior of cold rolled steel in hydrochloric acid,oxalic acid and nitric acid media in the presence of various concentrations of hexadecyltrimethylammonium bromide was studied using weight loss measurements.Results obtained revealed that hexadecyltrimethylammonium bromide is a very good inhibitor for cold rolled steel in hydrochloric acid,and the adsorption of the inhibitor on the cold rolled steel surface followed the Langmuir adsorption isotherm.Experimental data also indicated that the effect of hexadecyltrimethylammonium bromide on cold rolled steel corrosion is slight in oxalic acid solutions,and it was found that hexadecyltrimethylammonium bromide as an accelerator of cold rolled steel corrosion in nitric acid media.
Keywords:cold rolled steel  hexadecyltrimethylammonium bromide  hydrochloric acid  oxalic acid  nitric acid  inhibitive action  corrosion behavior
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