| 甲酸镁框架化合物的原位溶剂热合成及晶体结构(英文) |
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| 引用本文： | 张庆富,韩丹丹,傅式洲.甲酸镁框架化合物的原位溶剂热合成及晶体结构(英文)[J].聊城大学学报(自然科学版),2010,23(2):74-77. |
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| 作者姓名： | 张庆富 韩丹丹 傅式洲 |
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| 作者单位： | 聊城大学,化学化工学院,山东,聊城,252059 |
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| 摘 要： | 100℃条件下,通过溶剂热原位合成反应,氯化镁和N,N-二甲基甲酰胺在甲苯中生成了一种甲酸镁框架化合物,(C3H3MgO6)n·n(C2H6NH2);并用元素分析、红外光谱和X-射线单晶衍射对该化合物进行了表征.在该化物中,中心Mg(Ⅱ)离子和甲酸根阴离子构建了一个立方形的三维金属-有机框架结构,客体二甲胺阳离子占据在它的孔道中.
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| 关 键 词： | 镁 N N-二甲基甲酰胺 原位溶剂热反应 晶体结构 |
Solvothermal In Situ Synthesis and Crystal Structure of Polymeric Magnesium Formate,(C3H3MgO6)n·n(C2H6NH2) |
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| ZHANG Qing-fu,HAN Dan-dan,FU Shi-zhou.Solvothermal In Situ Synthesis and Crystal Structure of Polymeric Magnesium Formate,(C3H3MgO6)n·n(C2H6NH2)[J].Journal of Liaocheng University:Natural Science Edition,2010,23(2):74-77. |
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| Authors: | ZHANG Qing-fu HAN Dan-dan FU Shi-zhou |
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| Abstract: | A polymeric magnesium (Ⅱ) formate,(C3H3MgO6)n·n(C2H6NH2) (1) ,has been obtained by solvothermal in situ reaction of magnesium chloride and N,N-dimethylformamide in toluene at 100 ℃. Compound 1 has been characterized by elemental analysis,FT-IR and X-ray crystallographic diffraction analysis. In the crystal structure, a 3D metal-organic framework structure is constructed by Mg(Ⅱ) centers and formate groups,where the C2H6NH2 guests are located in the channels. |
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| Keywords: | Magnesium N N-dimethylformamide solvothermal in situ reaction crystal strucutre |
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