BFR-Ti和ZB协同阻燃隧道路面沥青的阻燃性能及机理

以钛酸酯改性沥青阻燃剂BFR-Ti和阻燃增效荆硼酸锌ZB为助荆,以SBS改性沥青为母体制备隧道阻燃沥青,通过氧指数法、烟密度法、锥形量热法和热重分析等方法系统研究了BFR-Ti与ZB协同阻燃SBS改性沥青的燃烧性能,探讨了二者的协同阻燃机理.结果表明,与SBS改性沥青/BFR-Ti相比,SBS改性沥青/BFR-Ti/ZB体系的氧指数略有上升,烟密度、热释放速率(HRR)、质量损失速率(MLR)以及有效燃烧热(EHC)等指标均明显下降,实际成炭量增加；SBS改性沥青/BFR-Ti具有显著的吸热阻燃机理和凝聚相阻燃机理的特征,SBS改性沥青/BFR-Ti/ZB是以凝聚相阻燃机理为主,兼具协效阻燃和吸热阻燃机理.

Study on flammability and flame-retardant mechanism of modified asphalt for tunnel pavement synergisticly flame retarded by BFR-Ti and ZB

Tunnel fire resistant asphalt can be prepared by mixing SBS modified asphalt and BFR-Ti/ZB. The combustion performances of the SBS modified asphalt/BFR-Ti/ZB and the synergism mechanism of the BFR-Ti and ZB are studied systematically through different methods, such as oxygen index (LOI) method, density of smoke, cone calorimetry, thermogravimetric analysis, etc. The result indicates that compared with SBS modifiedasphalt/BFR-Ti, BFR-Ti/ZB has synergistic effect which can make smoke density, heat release rate(HRR), mass loss rate(MLR) and effective heat of combustion(EHC) of SBS modified asphalt/BFR-Ti/ZB systems significantly decrease while the oxygen index of the SBS modified asphalt/BFR-Ti/ZB and the practice carbon content increase. SBS modified asphalt/BFR-Ti system has significant endothermic-antiflaming mechanism and condensed phase flame-retardance character. SBS modified-asphalt / BFR-Ti/ZB is based on the condensed phase flame-retardance mechanism while with synergistic flame-retardance and endothermic-antiflaming mechanism.