| 卟啉化合物的电化学性质 |
| |
| 引用本文： | 郑文琦,单凝,石莹岩,法焕宝,李迪,王杏乔.卟啉化合物的电化学性质[J].吉林大学学报(理学版),2011,49(5):944-948. |
| |
| 作者姓名： | 郑文琦 单凝 石莹岩 法焕宝 李迪 王杏乔 |
| |
| 作者单位： | 1. 吉林建筑工程学院 基础科学部, 长春 130118； 2. 吉林大学 化学学院, 长春 130021；3. 重庆大学 化学化工学院, 重庆 400044； 4. 清华大学 理学院, 北京 100084 |
| |
| 基金项目： | 吉林省教育厅“十一五”科学技术项目(批准号:2009417); 吉林建筑工程学院博士科研启动基金 |
| |
| 摘 要： | 合成2种在苯环对位连接性质不同取代基的卟啉单体和4种桥联基团性质各异的卟啉低聚物, 并利用循环伏安法研究上述卟啉单体和卟啉低聚物的电化学性质. 结果表明: 卟啉单体周边连接推电子取代基与连接吸电子取代基的卟啉单体相比电极电势正移; 比较卟啉低聚物电化学性质发现, 桥连基团的性质及整个卟啉分子的共轭程度对其电化学性质均有不同程度的影响.
|
| 关 键 词： | 卟啉 单体 低聚物 电化学性质 |
| 收稿时间： | 2011-01-09 |
Electrochemical Properties of Porphyrin Compounds |
| |
| ZHENG Wen-qi,SHAN Ning,SHI Ying-yan,FA Huan-bao,LI Di,WANG Xing-qiao.Electrochemical Properties of Porphyrin Compounds[J].Journal of Jilin University: Sci Ed,2011,49(5):944-948. |
| |
| Authors: | ZHENG Wen-qi SHAN Ning SHI Ying-yan FA Huan-bao LI Di WANG Xing-qiao |
| |
| Institution: | 1. Department of Basic Science, Jilin Institute of Architecture and Civil Engineering, Changchun 130118, China;2. College of Chemistry, Jilin University, Changchun 130021, China;3. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;4. School of Science, Tsinghua University, Beijing 100084, China |
| |
| Abstract: | The authors synthesized two porphyrin monomers with different substituents and four porphyrin oligomers with different bridge-linked reagents according to the literatures.The electrochemical properties of the porphyrins were studied by using cyclic voltammetry(CV) and compared with those of other porphyrin molecules under similar experimental conditions.It was found that porphyrin monomer linked with an electron-donating group was easy to reduce.The electrochemical properties of porphyrin oligomers were inf... |
| |
| Keywords: | porphyrin monomer oligomer electrochemical property |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《吉林大学学报(理学版)》浏览原始摘要信息 |
| 点击此处可从《吉林大学学报(理学版)》下载免费的PDF全文 |
|
