| 系列羟基苯基卟啉在碱体系中的性质 |
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| 引用本文： | 石莹岩,郭红卫,王杏乔.系列羟基苯基卟啉在碱体系中的性质[J].吉林大学学报(理学版),2010,48(3):491-494. |
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| 作者姓名： | 石莹岩 郭红卫 王杏乔 |
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| 作者单位： | 1. 吉林建筑工程学院 基础科学部, 长春 130021； 2. 吉林大学 化学学院, 长春 130021;3. 中国科学院 长春应用化学研究所电分析国家重点实验室, 长春 130021 |
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| 基金项目： | 吉林省"十一五"科学技术研究项目，吉林建筑工程学院博士科研启动基金 |
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| 摘 要： | 利用紫外-可见光谱、拉曼和红外光谱研究系列羟基苯基卟啉在碱体系中的性质.结果表明,碱与羟基苯基卟啉周边的羟基发生反应形成盐,而与卟啉中心环上的H没有相互作用,说明羟基苯基卟啉分子的中心环比较稳定,电荷主要分布在周边meso-位的取代基上,该位置易发生反应.
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| 关 键 词： | 羟基苯基卟啉 碱 紫外 可见光谱 红外光谱 拉曼光谱 |
| 收稿时间： | 2009-07-14 |
Properties of a Series of Hydroxyphenylporphyrins in Alkali |
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| SHI Ying-yan,GUO Hong-wei,WANG Xing-qiao.Properties of a Series of Hydroxyphenylporphyrins in Alkali[J].Journal of Jilin University: Sci Ed,2010,48(3):491-494. |
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| Authors: | SHI Ying-yan GUO Hong-wei WANG Xing-qiao |
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| Institution: | 1. Department of Basic Sciences, Jilin Institute of Architecture and Civil Engineering, Changchun 130021, China;2. College of Chemistry, Jilin University, Changchun 130021, China|3. State Key Laboratory of ElectroanalyticalChemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130021, China |
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| Abstract: | We studied the properties of a series of hydroxyphenylporphyrins in alkali via UV Visible, infrared spectroscopy and Raman spectroscopy. It was found that in the base system, the alkali reacted with the peripheral hydroxyls of hydroxyphenylporphyrin, forming the salt, while no interaction between alkali and H on the center of the porphyrin ring took place. This result proves that the center ring of the hydroxyphenylporphyrin ring was stable, electric charges of the porphyrin were mostly distributed on the circumambient substituent on the meso position where reaction easily took place react. |
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| Keywords: | hydroxyphenylporphyrin alkali UV Visible spectrum infrared spectroscopy Raman spectroscopy |
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