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化肥厂高浓度氨氮废水的处理和回用
引用本文:李晓萍,刘小波,金向军,林海波.化肥厂高浓度氨氮废水的处理和回用[J].吉林大学学报(理学版),2006,44(2):295-298.
作者姓名:李晓萍  刘小波  金向军  林海波
作者单位:(1. 吉林大学 化学学院, 长春 130021; 2. 白城师范学院 化学系, 吉林省 白城 137000)
摘    要:在实验室规模研究了通过生成鸟粪石(磷酸铵镁, MAP)去除氨氮工艺条件的影响. 加入磷酸和MgO产生MAP沉淀, pH值对其影响很大, pH值为9.0时氨氮去除效果最好. PO43-, Mg2+, NH4+的摩尔比为1 ∶1.5 ∶1时, 氨氮去除率较大并且可较好地回收氨生成鸟粪石. 此外, 物料的加入次序严重影响氨氮的去除. 两步沉淀工艺氨氮去除率达99.1%, 氨回收率为80.1%.

关 键 词:氨氮废水  鸟粪石  磷酸氨镁  废水处理  回用  化肥厂  
文章编号:1671-5489(2006)02-0295-04
收稿时间:2005-07-25
修稿时间:2005年7月25日

Treatment and Recovery of the High Concentration Ammonia-nitrogen Wastewater from Fertilizer Plant
LI Xiao-ping,LIU Xiao-bo,JIN Xiang-jun,LIN Hai-bo.Treatment and Recovery of the High Concentration Ammonia-nitrogen Wastewater from Fertilizer Plant[J].Journal of Jilin University: Sci Ed,2006,44(2):295-298.
Authors:LI Xiao-ping  LIU Xiao-bo  JIN Xiang-jun  LIN Hai-bo
Institution:(1. College of Chemistry, Jilin University, Changchun 130021, China; 2. Department of Chemistry, Baicheng Teachers College, Baicheng 137000, Jilin Province, China)
Abstract:The effects of processing conditions on NH4+-N(ammonia-nitrogen) removal to form struvite(magnesium ammonium phosphate, MAP) were studied in a laboratory scale. MAP precipitation was carried out by adding phosphoric acid and MgO. The effect of pH was significant and the highest removal was obtained at pH 9.0. A PO43-∶Mg2+ ∶NH4+ molar ratio of 1 ∶ 1.5 ∶1 was found to be beneficial for the higher removal of NH4+-N and the higher recovery of ammonia to form struvite. In addition, the feed in sequence of material significantly affects NH4+-N removal. It was shown that a highest NH4+-N removal of 99.1% and an ammonia recovery of 80.1% could be obtained by a two-step precipitation process.
Keywords:ammonia-nitrogen wastewater  struvite  magnesium ammonium phosphate  wastewater treatment  recovery  fertilizer
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