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自然水体生物膜吸附Mn2+过程中吸附液pH值的变化
引用本文:董德明,张菁菁,李鱼,花修艺,杨帆,刘淼,张君枝.自然水体生物膜吸附Mn2+过程中吸附液pH值的变化[J].吉林大学学报(理学版),2003,41(2):234-237.
作者姓名:董德明  张菁菁  李鱼  花修艺  杨帆  刘淼  张君枝
作者单位:吉林大学环境与资源学院, 长春 130023
基金项目:国家自然科学基金(批准号: 20077011)、国家教育部博士学科点专项基金(批准号: 20020183056)和高等学校骨干教师资助计划基金(批准号: 教技司 [2000]65号).
摘    要:利用自然水体培养的生物膜进行了微量矿物盐溶液、 ddH2O体系的Mn2+的吸附实验, 并用无Mn2+的微量矿物盐溶液、 ddH2O作对比, 研究自然水体生物膜吸附Mn2+过程中吸附液pH值的变化. 结果表明, 在吸附过程中, 4种吸附液的pH值都是先升后降至稳定, 微量矿物盐体系的p H值高于相应的ddH2O体系的pH值, 无Mn2+吸附液的pH 值高于有Mn2+的吸附液的pH值, 且可用氧化物表面吸附的配合模式描述自然水体生物膜吸附Mn2+过 程中吸附液pH值的变化.

关 键 词:自然水体  生物膜  Mn2+  pH值  吸附机制  
文章编号:1671-5489(2003)02-0234-04
收稿时间:2002-08-11
修稿时间:2002年8月11日

Changes of Solution pH During Mn2+ Adsorption to the Natural Surface Coatings
WTDONG De-ming,ZHANG Jing-jing,LI Yu,HUA Xiu-yi,YANG Fan,LIU Miao,ZHANG Ju n-zhi.Changes of Solution pH During Mn2+ Adsorption to the Natural Surface Coatings[J].Journal of Jilin University: Sci Ed,2003,41(2):234-237.
Authors:WTDONG De-ming  ZHANG Jing-jing  LI Yu  HUA Xiu-yi  YANG Fan  LIU Miao  ZHANG Ju n-zhi
Institution:College of Environment and Resources, Jilin University, Changchun 130023, China
Abstract:Adsorption of Mn2+ to natural surface coat ings developed in the South Lake was carried out for the purpose of investigatin g pH changes of different systematic solutions, which were prepared by minimal m ineral salts (MMS) and distilled-deionized water (dd water) with Mn2+ present and absent, respectively. The results show that the pH values of the four solutions employed increased remarkably during the initial adsorption perio d first, subsequently decreased to a stationary value gradually. In addition, the pH values of MMS solutions were higher than those of dd water solutions without MMS accordingly, and solutions without Mn2+ higher than those of solutions with Mn2+ presen t. The variety of pH in the study could be described by an oxide surface adsorp tion conjugate model.
Keywords:natural water  surface coating  Mn~(2+)  pH  adsorption mechanism
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