| 含二苯基吡啶基膦配体的Fe－Rh配合物的合成、测试及催化性能 |
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| 引用本文： | 方延全,赵维君,张书笈,杨丽梅,张正之,黄唯平,王桂林,田英芬.含二苯基吡啶基膦配体的Fe－Rh配合物的合成、测试及催化性能[J].南开大学学报,1995(1). |
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| 作者姓名： | 方延全 赵维君 张书笈 杨丽梅 张正之 黄唯平 王桂林 田英芬 |
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| 作者单位： | 南开大学化学系，天津师范大学化学系，天津教育学院化学系 |
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| 摘 要： | 二苯基吡啶基膦是个优良的双齿配体。用它制得了铁配合物和含铁－铑的双核配合物。铁－铑双核配合物作为甲醇羰基化制乙酸和乙酸甲酯的催化剂，转化率达１００％，选择性为９９％。对铁配合物和铁－铑双核配合物进行了红外、核磁和穆斯堡尔谱测定。
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| 关 键 词： | 配合物催化剂 配体 二苯基吡啶基膦配体 |
SYNTHESIS OF THE Fe-Rh BINUCIEAR COMPLEX CONTAINING DIPHENYL-PYRONYLPHOSPHINE LIGAND AND IT'S CATALYSIS PROPERTY FOR CARBONYLATION OF METHYL ALCOHOL |
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| Fang Yanquan, Zhao Weijun, Zhang Shuji,Yang Limei, Huang Wei ping.SYNTHESIS OF THE Fe-Rh BINUCIEAR COMPLEX CONTAINING DIPHENYL-PYRONYLPHOSPHINE LIGAND AND IT'S CATALYSIS PROPERTY FOR CARBONYLATION OF METHYL ALCOHOL[J].Acta Scientiarum Naturalium University Nankaiensis,1995(1). |
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| Authors: | Fang Yanquan Zhao Weijun Zhang Shuji Yang Limei Huang Wei ping |
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| Abstract: | Pheny1-Pyronylphosphine is a good dinod ligand. This ligand can react with iron compound to form complex. The Fe-Rh binuclear complex containing Pheny1-Pyronylphosphine was prepared. This Fe-Rh complex is a good catalyst for carbonylation of methanol to form aceticacid and methyl acetate. The conversion of methanol is 100% and selectivity is 99%. Phsicochemical studies including the infrared, nuclear magnetic resonance absorption and Mossboaur spectrum were performed on the Fe-Rh complex. |
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| Keywords: | complex catalyst ligand phenyl-pyronylphosphine |
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