| 二维层状钒氧化合物Co(bpy)(H2O)V2O6的水热合成和晶体结构 |
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| 引用本文： | 李杰,刘迎红,马鹏涛,王敬平.二维层状钒氧化合物Co(bpy)(H2O)V2O6的水热合成和晶体结构[J].河南大学学报(自然科学版),2006,36(3):33-36. |
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| 作者姓名： | 李杰 刘迎红 马鹏涛 王敬平 |
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| 作者单位： | 河南大学,化学化工学院分子与晶体工程研究所,河南,开封,475001 |
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| 基金项目： | 河南省高校新世纪优秀人才支持项目
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河南省高校青年骨干教师资助项目
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河南省教育厅科研项目 |
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| 摘 要： | 采用水热合成法合成了组成为Co(bpy)(H2O)V2O6(bpy=bipyridine)的钒氧化合物,并用红外光谱、元素分析和单晶X-射线衍射等手段对其进行了表征.结果表明:化合物的晶体属于正交晶系,Pca21空间群,a=0.922 3(10)nm,b=1.054 8(12)nm,c=1.439 7(16)nm,V=1.401(3)nm3,Z=4,R1=0.016 4.单晶结构解析表明,化合物具有由钒-氧锯齿链{V2O6}2nn-和n个Co(bpy)(H2O)2 单元通过氧原子共价连接而形成的二维层状结构.
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| 关 键 词： | 水热合成 钒氧化合物 层状结构 |
| 文章编号： | 1003-4978（2006）03-0033-04 |
| 收稿时间： | 2006-04-08 |
| 修稿时间： | 2006年4月8日 |
Hydrothermal Synthesis and Crystal Structure of a Two-Dimensional (2D) Layered Vanadium Oxide: Co(bpy)(H2O)V2O6 |
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| LI Jie,LIU Ying-hong,MA Peng-tao,WANG Jing-ping.Hydrothermal Synthesis and Crystal Structure of a Two-Dimensional (2D) Layered Vanadium Oxide: Co(bpy)(H2O)V2O6[J].Journal of Henan University(Natural Science),2006,36(3):33-36. |
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| Authors: | LI Jie LIU Ying-hong MA Peng-tao WANG Jing-ping |
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| Institution: | Institute of Molecular and Crystal Engineering, college of Chemistry and Chemical Engineering Henan University, Henan Kaifeng 475001, China |
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| Abstract: | A vanadium oxide,Co(bpy)(H_(2)O)V_(2)O_(6)(bpy = bipyridine),was hydrothermally synthesized and subject to IR spectroscopy,elemental analysis and single-crystal X-ray diffraction.The result indicates that this compound crystallizes in orthorhombic space group Pca2_(1)with a=0.922 3(10) nm,b=1.054 8(12) nm,c=(1.439 7)(16) nm,V=1.401(3) nm~(3),Z=4,R_(1)=0.016 4.X-ray crystallography shows that the compound consists of unique two-dimensional layers constructed from vanadium oxide zigzag chains {V_(2)O_(6)}~(2n-)_(n) and covalently linked by Co(bpy)(H_(2)O)~(2 )subunits via oxygen atoms. |
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| Keywords: | Hydrothermal synthesis Vanadium oxide Layered structure |
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