| 三维锰钒配位聚合物Mn_2(phen)_2(VO_3)_4(H_2O)_2的水热合成与光电子能谱的表征 |
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| 引用本文： | 齐艳娟,郭飞君.三维锰钒配位聚合物Mn_2(phen)_2(VO_3)_4(H_2O)_2的水热合成与光电子能谱的表征[J].长春师范学院学报,2005(12). |
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| 作者姓名： | 齐艳娟 郭飞君 |
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| 作者单位： | 长春师范学院化学学院 长春师范学院化学学院 吉林长春 吉林长春 |
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| 摘 要： | 三维锰钒配位聚合物Mn2(phen)2(VO3)4(H2O)2在水热的条件下被合成出来,并在元素分析、红外光谱分析、光电子能谱分析和X-射线衍射方面进行了结构表征。X-射线分析表明,此化合物是三维结构。光电子能谱分析结果显示标题化合物显示出了有意义的信号,g值为1.997说明分子中V原子呈现 4价氧化态。
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| 关 键 词： | 锰钒配位聚合物 光电子能谱 氧化态 |
The Hydrothermal Synthesis and ESR Spectra of Three-Dimensional Manganese-Vanadium Complex Mn_2(phen)_2(VO_3)_4(H_2O)_2 |
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| QI Yan-juan,GUO Fei-jun.The Hydrothermal Synthesis and ESR Spectra of Three-Dimensional Manganese-Vanadium Complex Mn_2(phen)_2(VO_3)_4(H_2O)_2[J].Journal of Changchun Teachers College,2005(12). |
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| Authors: | QI Yan-juan GUO Fei-jun |
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| Abstract: | A Novel Three-Dimensional Manganese-Vanadium Complex Mn_2(phen)_2(VO_3)_4(H_2O)_2 was prepared under hydrothermal conditions and characterized by elemental analyses,IR spectra,ESR analysis,and single-crystal X-ray diffraction analysis.X-ray crystal analyses reveal that the title compound posses a three dimensional framework.The ESR analysis shows that the title compound exhibited significant paramagnetic signals.The value ofg(g=1.997)suggests that the V atoms are in the +4 oxidation state. |
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| Keywords: | manganese-vanadium complex ESR oxidation state |
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