| 氢化诺卜醇及其羧酸酯的合成与结构分析 |
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| 引用本文： | 赵玲华,刘显亮,肖转泉,陈金珠,王宗德,范国荣,陈尚钘.氢化诺卜醇及其羧酸酯的合成与结构分析[J].江西师范大学学报(自然科学版),2012(1):12-15. |
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| 作者姓名： | 赵玲华 刘显亮 肖转泉 陈金珠 王宗德 范国荣 陈尚钘 |
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| 作者单位： | 江西农业大学林学院;江西师范大学学报杂志社;江西师范大学化学化工学院;江西农业大学理学院 |
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| 基金项目： | 国家自然科学基金(30860223,31060101);教育部留学回国人员科研启动基金([2010]1561);江西省青年科学家(井冈之星)培养对象计划资助项目 |
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| 摘 要： | 诺卜醇经Ni(R)催化氢化合成氢化诺卜醇,氢化诺卜醇与7种羧酸进行酯化反应合成7种羧酸酯,产率均在90%以上,GC纯度达98%.对合成的羧酸酯均进行了IR、1H NMR、13C NMR与MS分析。
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| 关 键 词： | 诺卜醇 氢化诺卜醇 催化氢化 酯化 结构分析 |
The Synthesis and Structural Analysis for Hydronopol and Its Carboxylic Ethers |
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| ZHAO Ling-hua,LIU Xian-liang,XIAO Zhuan-quan,CHEN Jin-zhu,WANG Zong-de,FAN Guo-rong,CHEN Shang-xing.The Synthesis and Structural Analysis for Hydronopol and Its Carboxylic Ethers[J].Journal of Jiangxi Normal University (Natural Sciences Edition),2012(1):12-15. |
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| Authors: | ZHAO Ling-hua LIU Xian-liang XIAO Zhuan-quan CHEN Jin-zhu WANG Zong-de FAN Guo-rong CHEN Shang-xing |
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| Institution: | 1(1.College of Forestry,Jiangxi Agricultural University,Nanchang Jiangxi 330045,China;2.Periodical Office of Journal,Jiangxi Normal Universitry,Nanchang Jiangxi 330027,China;3.College of Chemistry,Jiangxi Normal University,Nanchang Jiangxi 330027,China;4.College of Science,Jiangxi Agricultural University,Nanchang Jiangxi 330045,China) |
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| Abstract: | Hydronopol was prepared from the hydrogenation of nopol in the presence of Raney Ni.And hy-dronopol reacts with 7 different kinds of carboxylic acids to produce new compounds of hydronopyl carboxylic ether series.The yield of the products(GC content were over 98%) were not less than 90%.Identification and structural analysis were done using IR,1H NMR,13C NMR and MS methods. |
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| Keywords: | nopol hydronopol catalytic hydrogenation esterification structural analysis |
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