| 聚合物负载的炔基硒醚试剂参与(Z)-1,2-二取代乙烯的固相有机合成 |
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| 引用本文： | 汪秋英,罗秋燕,陈国华,林淑英,刘晓玲.聚合物负载的炔基硒醚试剂参与(Z)-1,2-二取代乙烯的固相有机合成[J].江西师范大学学报(自然科学版),2004,28(2):126-128,150. |
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| 作者姓名： | 汪秋英 罗秋燕 陈国华 林淑英 刘晓玲 |
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| 作者单位： | 1. 江西师范大学,化学学院,江西,南昌,330027
2. 井冈山师范学院,化学系,江西,吉安,343009 |
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| 基金项目： | 江西省自然科学基金(001109)以及江西师范大学青年成长基金资助项目. |
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| 摘 要： | 聚苯乙烯负载硒溴与炔基锂反应合成聚苯乙烯负载炔基硒醚，再与二环己基硼烷反应制得聚苯乙烯负载顺式烯基硒醚；此负载型烯基硒醚在NiCl2(PPh3)2存在下与格氏试剂发生偶联反应，提供了一种有效的(z)-1，2-二取代乙烯的固相有机合成方法，
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| 关 键 词： | 固相有机合成 聚合物试剂 炔基硒醚 烯基硒醚 偶联反应 （z）-1，2-二取代乙烯 组合化学 |
| 文章编号： | 1000-5862(2004)02-0126-03 |
Solid-Phase Organic Synthesis of (Z)-1,2-Disubstituted Ethenes from Polymer-Supported Alkynyl Selenide |
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| WANG Qiu-ying,LUO Qiu-yan,CHEN Guo-hua,LIN Shu-ying,LIU Xiao-ling.Solid-Phase Organic Synthesis of (Z)-1,2-Disubstituted Ethenes from Polymer-Supported Alkynyl Selenide[J].Journal of Jiangxi Normal University (Natural Sciences Edition),2004,28(2):126-128,150. |
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| Authors: | WANG Qiu-ying LUO Qiu-yan CHEN Guo-hua LIN Shu-ying LIU Xiao-ling |
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| Institution: | WANG Qiu-ying~1,LUO Qiu-yan~2,CHEN Guo-hua~1,LIN Shu-ying~1,LIU Xiao-ling~1 |
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| Abstract: | Treatment of polystyrene-supported selenium ,bromide with lithium acetylides afforded polystyrene-supported selenoacetylene, which reacted with dicyclohexylborane giving a way for stereoselective synthesis of polymer-supported (Z)- vinylic selenides. Cross-coupling reaction of polymer-supported (Z)- vinylic selenides with Grignard reagents in the presence of NiCl_2(PPh_3)_2 as catalyzed yielded (Z)-1,2-disubstituted ethenes on solid-phase. |
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| Keywords: | solid-phase organic synthesis polymer-supported reagent alkynyl selenide vinylic selenides cross-coupling reaction (Z)-1 2-disubstituted ethenes |
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