| [Ni(phen)_3]_2[NiMo_(12)P_8O_(62)H_(18)]单晶材料催化合成阿司匹林的研究 |
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| 引用本文： | 张羽男,张云杰,李达,张磊,杨铭,刘红.[Ni(phen)_3]_2[NiMo_(12)P_8O_(62)H_(18)]单晶材料催化合成阿司匹林的研究[J].佳木斯大学学报,2014(5):726-728. |
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| 作者姓名： | 张羽男 张云杰 李达 张磊 杨铭 刘红 |
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| 作者单位： | 佳木斯大学药学院,黑龙江 佳木斯,154007 |
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| 基金项目： | 黑龙江省教育厅科学技术研究项目(12511543)． |
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| 摘 要： | 采用水热合成法制备Ni(phen)3]2NiMo12P8O62H18]单晶材料,通过考察反应温度、时间及催化剂用量等影响因素,确定了其催化合成阿司匹林的最佳条件为催化剂用量为0.09g,反应温度为80℃,反应时间为15min.表明Ni(phen)3]2NiMo12P8O62H18]单晶材料是一种催化合成阿司匹林的绿色、高效催化剂,可以为解决当前硫酸催化合成阿司匹林所产生的低效、污染及高成本的问题提供参考.
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| 关 键 词： | 磷钼氧簇合物 单晶 阿司匹林 催化 |
Catalytic Synthesis of Aspirin by [ Ni(phen) 3 ] 2 [ NiMo12 P8 O62 H18 ] Monocrystalline Material |
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| ZHANG Yu-nan,ZHANG Yun-jie,LI Da,ZHANG Lei,YANG Ming,LIU Hong.Catalytic Synthesis of Aspirin by [ Ni(phen) 3 ] 2 [ NiMo12 P8 O62 H18 ] Monocrystalline Material[J].Journal of Jiamusi University(Natural Science Edition),2014(5):726-728. |
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| Authors: | ZHANG Yu-nan ZHANG Yun-jie LI Da ZHANG Lei YANG Ming LIU Hong |
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| Institution: | ( College of Pharmacy, Jiamusl University, Jlamusi 154007, China) |
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| Abstract: | In this paper,Ni（phen）3]2NiMo12P8O62H18] monocrystalline material was synthesized by hydrothermal synthesis method .Factors of reaction temperature , reaction time and catalyst dosage were investiga-ted.The best experimental condition was determined：catalyst dose is 0.09g, temperature is 80℃, and time is 15min.The results showed that Ni（phen）3]2NiMo12P8O62H18] monocrystalline material is an environmentally friendly and highly efficient catalyst , which could supply references to solve the problems of catalytic synthesis of Aspirin by concentrated sulfuric acid , such as inefficiency , pollution and high cost . |
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| Keywords: | molybdenum phosphate oxide clusters monocrystalline aspirin catalytic |
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