| 茂钛催化剂的合成、选择及加氢反应机理探讨 |
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| 引用本文： | 贺小进,李伟,吴晓萍,陈建军,王郁,王爱东,胡保利,赵晓冬.茂钛催化剂的合成、选择及加氢反应机理探讨[J].宁夏大学学报(自然科学版),2001,22(2):238-239. |
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| 作者姓名： | 贺小进 李伟 吴晓萍 陈建军 王郁 王爱东 胡保利 赵晓冬 |
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| 作者单位： | 中国石化北京燕山石油化工公司研究院, |
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| 基金项目： | 中国石油化工集团公司攻关项目 (4 9992 7) |
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| 摘 要： | 合成了8种SBS加氢茂钛催化剂，其中二氯二茂钛和二对甲苯基二茂钛活性较好。催化剂用量为0．2－0．4mmol/(100g)聚合物时，二烯烃段加氢度≥98%，苯环加氢度≤2%，同时探讨了加氢反应机理。
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| 关 键 词： | SBS SEBS 茂钛催化剂 加氢催化剂 合成 加氢反应机理 二氯二茂钛 |
| 文章编号： | 0253-2328(2001)02-0238-02 |
| 修稿时间： | 2001年5月1日 |
Study on syntheses, selection and the hydrogenated reaction mechanism of titanocene |
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| HE Xiao-jin,LI Wei,WU Xiao-ping,CHEN Jian-jun,WANG Yu,WANG Ai-dong,HU Bao-li,ZHAO Xiao-dong.Study on syntheses, selection and the hydrogenated reaction mechanism of titanocene[J].Journal of Ningxia University(Natural Science Edition),2001,22(2):238-239. |
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| Authors: | HE Xiao-jin LI Wei WU Xiao-ping CHEN Jian-jun WANG Yu WANG Ai-dong HU Bao-li ZHAO Xiao-dong |
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| Abstract: | kinds titanocene hydrogenation catalysts of SBS were synthesized.Biscyclopent-adieneyl titanium dichloride and di-p-tolybiscyclopentadieneyl titanium are good catalysts.They have high hydrogenation activity and good selectivity. The hydrogenation degree of diene in SBS is more than 98%,and the hydrogenation degree of styrene in SBS less than 2%.And also the mechanism of hydrogenation reaction were also investigated. |
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| Keywords: | SBS SEBS titanocene hydrogenation degree |
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