| 固体三氯三(乙二胺)合钴和三氯三(乙二胺)合铬的红外激光离解反应 |
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| 引用本文： | 王永高,刘维铭.固体三氯三(乙二胺)合钴和三氯三(乙二胺)合铬的红外激光离解反应[J].西南科技大学学报,1990(4). |
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| 作者姓名： | 王永高 刘维铭 |
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| 作者单位： | 四川建材学院硅工系
(王永高)，四川大学(刘维铭) |
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| 摘 要： | 本文研究了固体Co(en)_3Cl_3和Cr(en)_3Cl_3(这里en代表乙二胺)在TEA CO_2激光作用下的红外多光子离解反应,其反应产物分别为光化学还原产物CoCl_2和二(乙二胺)配合物Cr(en)_2Cl_2]Cl。作者认为 Co(en)_3Cl_3和 Cr(en)_3Cl_3的红外多光子离解反应是一激光热解过程。
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| 关 键 词： | 乙二胺 激光 配合物 |
IR Laser Decomposition Reaction of Silid State Co(en)_3Cl_3and Cr(en)_3Cl_3 |
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| Wang Yong gao.IR Laser Decomposition Reaction of Silid State Co(en)_3Cl_3and Cr(en)_3Cl_3[J].Journal of Southwest University of Science and Technology,1990(4). |
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| Authors: | Wang Yong gao |
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| Institution: | Wang Yong gao (Sichuan Institute of Building Materials)
Liu Wei ming (Sichuan University) |
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| Abstract: | The IR multiphoton decomposition reactions of the solid state Co(en3Cl3and Cr(cn)3Cl3by using TEA CO2laser have been investigated in this paper, their reaction products are photochemicaal reduction product CoC2and di(cthylencdiamine) complex Cr(cn)2Cl2]Cl, respectively. The authors believe that the reaction of Co(cn)3Cl3or Cr(cm)3Cl3is a laser thermal decomposition process. |
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| Keywords: | ethylencdiamine laser complex |
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