| 多核金属磺化酞菁催化下的环己烯环氧化反应 |
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| 引用本文： | 孙强,张天云.多核金属磺化酞菁催化下的环己烯环氧化反应[J].东北师大学报(自然科学版),1995(1):79-82. |
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| 作者姓名： | 孙强 张天云 |
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| 作者单位： | 东北师范大学化学系 |
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| 摘 要： | 尝试使用９种多核金属磺化酞菁催化环已烯的环氧化反应，结果表明它们对环已烯在氧气作氧源的环氧化反应有催化作用，通过正交试验，发现以多核磺化酞菁镍（Ⅱ）、多核磺化酞菁钴（Ⅱ）和多核磺化酞菁铁（Ⅲ）的催化活性为佳。
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| 关 键 词： | 多核金属 磺化酞菁催化 环己烯 环氧化 配合物 |
Epoxidation of Cyclohexene Catalyzed by Multi-Nuclear Metal Sulfo-Phthalocyanine |
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| Sun Qiang,Zhang Tianyun,Wang Liping,Yao Xiaohua,Su Yongcheng,Sao Changlu,Zhang zhenquan.Epoxidation of Cyclohexene Catalyzed by Multi-Nuclear Metal Sulfo-Phthalocyanine[J].Journal of Northeast Normal University (Natural Science Edition),1995(1):79-82. |
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| Authors: | Sun Qiang Zhang Tianyun Wang Liping Yao Xiaohua Su Yongcheng Sao Changlu Zhang zhenquan |
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| Abstract: | Nine multi-nuclear metal sulfo-phthalocyanines had been used as catalysts for epoxidation of cyclohexene. The experiment results showed that they have catalytic activity for epoxidation of cyclohexene with molecular oxygen and multi-nuclear ferric sulfo-phthalocyanine, multi-nuclear cobaltous sulfo-phthalocyanine and multi-nuclear nickelous sulfo-phthalocyanine have better catalytic activity for epoxidation of cyclohexene |
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| Keywords: | catalyzed by multi-nuclear metal sulfo-phthalo cyanines expoxidation cyclohexene molecular oxygen orthogonal test |
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