| 组氨酸的Keggin结构杂多金属氧酸盐的合成及性质研究 |
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| 引用本文： | 郭树荣,王恩波.组氨酸的Keggin结构杂多金属氧酸盐的合成及性质研究[J].东北师大学报(自然科学版),1999(3):116-119. |
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| 作者姓名： | 郭树荣 王恩波 |
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| 作者单位： | 东北师范大学化学学院!吉林长春130024 |
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| 摘 要： | 首次合成了组氨酸的Ｋｅｇｇｉｎ结构（ＸＭ１２Ｏ４０＾ｎ－，Ｘ＝Ｐ，Ｓｉ，Ｍ＝Ｗ，Ｍｏ）３种杂多金属氧酸盐化合物，用元素分析、ＩＲ、ＵＶ、ＴＧ－ＤＴＡ等方法对标事物进行了表征，结果表明该类化合物仍保持Ｋｅｇｇｉｎ结构、杂多酸阴离子和氨基酸靠静电作用相结合。
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| 关 键 词： | 组氨酸 杂多金属氧酸盐 合成 表征 Keggin结构 |
Study on synthesis and properties of histidine heteropolyoxometalates with Keegin structure |
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| GUO Shu rong,WANG En bo,YOU Wan sheng,LIU Jing ha,LUAN Guo you.Study on synthesis and properties of histidine heteropolyoxometalates with Keegin structure[J].Journal of Northeast Normal University (Natural Science Edition),1999(3):116-119. |
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| Authors: | GUO Shu rong WANG En bo YOU Wan sheng LIU Jing ha LUAN Guo you |
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| Abstract: | It was first reported that three compounds of histidine heteropolyoxometalates with the Keggin structure (XM 12 O 40 n - ,X=P,Si,M=W,Mo) had been synthesized. They were characterized by means of elementary analysis, IR, UV, TG-DTA.It was known that XMO 40 n - anions with a Keggin structure was kept unchanged and the anion and histidine were combined by means of electrostafic forces. |
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| Keywords: | histidine heteropolyoxometalates synthesis characterization |
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