| 有机锡连续法催化合成乙酸乙酯的研究 |
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| 引用本文： | 张云峰,张效霓,朱东升,李晓东,邵奎占.有机锡连续法催化合成乙酸乙酯的研究[J].东北师大学报(自然科学版),2001,33(1):122-124. |
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| 作者姓名： | 张云峰 张效霓 朱东升 李晓东 邵奎占 |
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| 作者单位： | 东北师范大学化学学院, |
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| 基金项目： | 吉林省科委应用研究项目! ( 990 1 1 1 ) |
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| 摘 要： | 对有机锡连续催化合成乙酸乙酯进行了较深入的研究，结果表明有锡连续催化酯化反应时的催化活性比硫酸略低，但使用寿命（115h)比硫酸长，底物不碳化，催化剂可重复使用等优点，而且酯产高于硫酸。
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| 关 键 词： | β－甲氧羰乙基三氯化锡 连续法 乙酸乙酯 催化合成 催化剂 |
| 文章编号： | 1000-1832(2000)04-0122-03 |
| 修稿时间： | 2000年9月6日 |
Study on continuous process for synthesis of ethyl acetate with organo-tin as catalysts |
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| ZHANG Yun-feng,ZHANG Xiao-ni,ZHU Dong-sheng,LI Xiao-dong,SHAO Kui-zhan.Study on continuous process for synthesis of ethyl acetate with organo-tin as catalysts[J].Journal of Northeast Normal University (Natural Science Edition),2001,33(1):122-124. |
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| Authors: | ZHANG Yun-feng ZHANG Xiao-ni ZHU Dong-sheng LI Xiao-dong SHAO Kui-zhan |
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| Abstract: | The continuous process was used to synthesized ethyl acetate by the esterification of ethyl alcohol and acetic acid catalyzed by organo-tin trichlorides was studied. The results showed that the catalytic activity of the continuous process for synthesizing ethyl acetate was a little lower than that of the sulfuric acid, but the life of the catalyst 115 h was much longer than that of the latter. The reactants were not carbonized and the catalyst cold be reused for many times. The yield was higher than that of sulfuric acid. |
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| Keywords: | methoxycarbonylethyltin thrichloride catalysis continuous process ethyl acetate |
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