静电纺壳聚糖/PVA共混纤维的微细结构 |
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引用本文: | 夏艳杰,邱芯薇,潘志娟,陈立英.静电纺壳聚糖/PVA共混纤维的微细结构[J].南通大学学报(自然科学版),2006,5(1):34-37,42. |
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作者姓名: | 夏艳杰 邱芯薇 潘志娟 陈立英 |
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作者单位: | 苏州大学,材料工程学院,江苏,苏州,215021 |
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摘 要: | 文章主要研究静电纺工艺对壳聚糖/聚乙烯醇(PVA)共混纤维形态结构和聚集态结构的影响.研究表明:以甲酸为溶剂时,静电纺壳聚糖/PVA共混纤维的直径随着电压的增大有减小的趋势,喷丝头到接收屏之间的距离(C-SD)的增加有利于珠状物的减少,但使纤维细度的均匀性下降;以乙酸为溶剂时,静电纺壳聚糖/PVA共混纤维虽然呈连续的分布,但其上有一定数量的珠状物,增加C-SD,珠状物减少;随着电压和C-SD的增加,静电纺壳聚糖-乙酸/PVA共混纤维的结晶度增加.
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关 键 词: | 壳聚糖 静电纺丝 PVA 形态结构 聚集态结构 |
文章编号: | 1673-2340(2006)01-0034-04 |
The Microstructure of Electrospun Chitosan/PVA Nanofibres |
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Authors: | XIA Yan-jie QIU Xin-wei PAN Zhi-juan CHEN Li-ying |
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Abstract: | The effect of electrospinning technologies on the morphology structure and molecular conformation of electrospun chitosan/poly(vinyl alcohol)(PVA) fibres were investigated.The results showed that when the spinning solvent was formic acid,the diameter of electrospun chitosan/PVA fibres decreased with the increasing of the voltage,and the enhancing of the distance between capillary and screen(C-SD)was propitious to reduce the quantity of the beads.However,the uniformity of the diameter of the fibres decreased.When the solvent was acetic acid,the distribution of electrospun chitosan/PVA fibers was continuous,but there were a number of beads.With the increasing of the voltage and the C-SD,the crystal degree of electrospun chitosan-acetic acid/PVA fibers increased. |
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Keywords: | chitosan electrospinning PVA morphology structure molecular conformation |
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