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静电纺壳聚糖/PVA共混纤维的微细结构
引用本文:夏艳杰,邱芯薇,潘志娟,陈立英.静电纺壳聚糖/PVA共混纤维的微细结构[J].南通大学学报(自然科学版),2006,5(1):34-37,42.
作者姓名:夏艳杰  邱芯薇  潘志娟  陈立英
作者单位:苏州大学,材料工程学院,江苏,苏州,215021
摘    要:文章主要研究静电纺工艺对壳聚糖/聚乙烯醇(PVA)共混纤维形态结构和聚集态结构的影响.研究表明:以甲酸为溶剂时,静电纺壳聚糖/PVA共混纤维的直径随着电压的增大有减小的趋势,喷丝头到接收屏之间的距离(C-SD)的增加有利于珠状物的减少,但使纤维细度的均匀性下降;以乙酸为溶剂时,静电纺壳聚糖/PVA共混纤维虽然呈连续的分布,但其上有一定数量的珠状物,增加C-SD,珠状物减少;随着电压和C-SD的增加,静电纺壳聚糖-乙酸/PVA共混纤维的结晶度增加.

关 键 词:壳聚糖  静电纺丝  PVA  形态结构  聚集态结构
文章编号:1673-2340(2006)01-0034-04

The Microstructure of Electrospun Chitosan/PVA Nanofibres
Authors:XIA Yan-jie  QIU Xin-wei  PAN Zhi-juan  CHEN Li-ying
Abstract:The effect of electrospinning technologies on the morphology structure and molecular conformation of electrospun chitosan/poly(vinyl alcohol)(PVA) fibres were investigated.The results showed that when the spinning solvent was formic acid,the diameter of electrospun chitosan/PVA fibres decreased with the increasing of the voltage,and the enhancing of the distance between capillary and screen(C-SD)was propitious to reduce the quantity of the beads.However,the uniformity of the diameter of the fibres decreased.When the solvent was acetic acid,the distribution of electrospun chitosan/PVA fibers was continuous,but there were a number of beads.With the increasing of the voltage and the C-SD,the crystal degree of electrospun chitosan-acetic acid/PVA fibers increased.
Keywords:chitosan  electrospinning  PVA  morphology structure  molecular conformation
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