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高氯酸-重铬酸钾无汞测铁法
引用本文:阎俊英,蒋兰宏.高氯酸-重铬酸钾无汞测铁法[J].河北师范大学学报(自然科学版),2002,26(2):167-168.
作者姓名:阎俊英  蒋兰宏
作者单位:河北师范大学化学学院,河北,石家庄,050091
摘    要:提出了以高氯酸代替经典方法中的二氯化汞氧化过量的氯化亚锡,重铬酸钾标准溶液滴定Fe^2 的无汞盐测定铁矿石中全铁的新方法。用该法测定了铁矿石中的铁含量,其相对偏差为0.09%,且测定结果与经典法非常一致。

关 键 词:高氯酸  无汞测铁法  重铬酸钾滴定  铁矿石  含量测定  氯化亚锡
文章编号:1000-5854(2002)02-0167-02
修稿时间:2001年6月14日

The Method of No Mercury Salt Determination Iron by Perchloric Acid-potassium Dichromate
YAN Jun-ying,JIANG Lan-hong.The Method of No Mercury Salt Determination Iron by Perchloric Acid-potassium Dichromate[J].Journal of Hebei Normal University,2002,26(2):167-168.
Authors:YAN Jun-ying  JIANG Lan-hong
Abstract:The new method was advanced to determine iron of the iron ore.In the method,mercuric chloric solution of the classical method was replaced with perchloric acid solution to oxide the little excess stannous chloride and Fe 2+ was titrated with potassium dichromate standard solution.The method was been applied to determine iron of the iron ore with the relative standard deviations of 0.09%. The results compare with classical method.
Keywords:perchloric acid  no mercury salt determination iron  potassirm dichromate titration  
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