| 一种新的六氮杂异伍兹烷衍生物的合成与表征 |
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| 引用本文： | 孙成辉,白军红,方涛,曹克广,赵信岐.一种新的六氮杂异伍兹烷衍生物的合成与表征[J].北京理工大学学报,2004,24(3):270-271. |
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| 作者姓名： | 孙成辉 白军红 方涛 曹克广 赵信岐 |
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| 作者单位： | 北京理工大学,材料科学与工程学院,北京,100081;北京理工大学,材料科学与工程学院,北京,100081;北京理工大学,材料科学与工程学院,北京,100081;北京理工大学,材料科学与工程学院,北京,100081;北京理工大学,材料科学与工程学院,北京,100081 |
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| 摘 要： | 为了探索六硝基六氮杂异伍兹烷(HNIW,CL-20)的硝化前体四乙酰基六氮杂异伍兹烷(TAIW)的反应性,以四乙酰基六氮杂异伍兹烷为原料,与甲醛进行胺醛缩合,生成一种新型六氮杂异伍兹烷衍生物:2,6,8,12-四乙酰基-14-氧杂-2,4,6,8,10,12-六氮杂五环5.5.3.0.05,9.03,11]十五烷,并用元素分析,IR,1H NMR,13C NMR,MS对其结构进行了表征.
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| 关 键 词： | 六氮杂异伍兹烷衍生物 合成法 表征 |
| 文章编号： | 1001-0645(2004)03-0270-03 |
| 收稿时间： | 5/9/2003 12:00:00 AM |
Synthesis and Characterization of a New Derivative of Hexaazaisowurtzitane |
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| SUN Cheng-hui,BAI Jun-hong,FANG Tao,CAO Ke-guang and ZHAO Xin-qi.Synthesis and Characterization of a New Derivative of Hexaazaisowurtzitane[J].Journal of Beijing Institute of Technology(Natural Science Edition),2004,24(3):270-271. |
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| Authors: | SUN Cheng-hui BAI Jun-hong FANG Tao CAO Ke-guang and ZHAO Xin-qi |
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| Institution: | School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China |
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| Abstract: | In order to explore the reactivity of tetraacetylhexaazaisowurtzitane (TAIW), an important nitrolyzable precursor for the synthesis of CL-20, it was condensed with aqueous formaldehyde to give a new hexaazaisowurtzitane derivative, 2,6,8,12-tetraactyl-14-oxo-2,4,6,8,10,12-hexaazapentacyclo () pentadecane. The new compound was struc-turally characterized by elemental analysis, IR, ()~1H NMR, ()~(13)C NMR and MS. |
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| Keywords: | hexaazaisowurtzitane derivative synthesis characterization |
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