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碳糊修饰电极阳极溶出伏安法测定痕量汞
引用本文:莫健伟,张谷兰,姚兴东,周性尧.碳糊修饰电极阳极溶出伏安法测定痕量汞[J].汕头大学学报(自然科学版),1995,10(1):84-87.
作者姓名:莫健伟  张谷兰  姚兴东  周性尧
作者单位:汕头大学测试中心,武汉大学化学系
摘    要:本文对碳糊修饰电极的制备进行了研究并用该电极阳极溶出伏安法测定痕量汞.结果表明:碳糊修饰电极测汞的灵敏度比碳糊电极的高得多,测汞的线性范围20×10-9g/ml-10×10-6g/ml,检测限5×10-9g/ml;本方法选择性好,应用于水样分析,结果满意.

关 键 词:修饰电极  溶出优安法  

Anodic stripping voltammetry for the determination of trace mercury by modified carbon paste electrode
Mo Jianwei,Zhang Gulan,Yao Xingdong.Anodic stripping voltammetry for the determination of trace mercury by modified carbon paste electrode[J].Journal of Shantou University(Natural Science Edition),1995,10(1):84-87.
Authors:Mo Jianwei  Zhang Gulan  Yao Xingdong
Abstract:This work studies the preparation of modified carbon paste electrode and suggests a new anodic stripping voltammetry for the determination of trace mercury by the modified carbon paste electrode. The modified electrode has much higher sensitivity to mercury determination than a carbon paste electrode. There is a good linear relationship between peak height and Hg concentration in the range of 20 ×10-9 - 10 ×10-6g/ml with the detection limit of 5×10-9g/ml. The method has good selectivity and satisfactory results have been obtained in determination of mercury in water samples.
Keywords:modified electrode  stripping voltammetry  mercury
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