| 新型N-取代-1,6-亚甲基桥[10]轮烯-3,4-二甲酰亚胺的合成 |
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| 引用本文： | 金锋,刘建军,陈海平,左胜利.新型N-取代-1,6-亚甲基桥[10]轮烯-3,4-二甲酰亚胺的合成[J].北京化工大学学报(自然科学版),2010,37(1):28-31. |
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| 作者姓名： | 金锋 刘建军 陈海平 左胜利 |
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| 作者单位： | 北京化工大学 理学院， 北京 100029 |
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| 摘 要： | 以1,6-亚甲基桥10]轮烯-3,4-二羧酸乙酯为原料,经皂化、酸化直接得到了一种新型中间体1,6-亚甲基桥10]轮烯-3,4-二甲酸酐,该酸酐与相应的伯胺(苯胺,苄胺,苯乙胺,正丁胺)在醋酸中回流3 h,简便的合成了新型N-取代-1,6-亚甲基桥10]轮烯-3,4-二甲酰亚胺,并用1H-NMR,13C-NMR,MS及HRMS等波谱进行了表征验证。
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| 关 键 词： | 1 6-亚甲基桥[10]轮烯 二甲酰亚胺 波谱 |
| 收稿时间： | 2009-03-26 |
A novel synthesis of N-substituted-1, 6-methano [10] annulene-3,4-dicarboximides |
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| JIN Feng,LIU JianJun,CHEN HaiPing,ZUO ShengLi.A novel synthesis of N-substituted-1, 6-methano [10] annulene-3,4-dicarboximides[J].Journal of Beijing University of Chemical Technology,2010,37(1):28-31. |
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| Authors: | JIN Feng LIU JianJun CHEN HaiPing ZUO ShengLi |
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| Institution: | School of Science, Beijing University of Chemical Technology, Beijing 100029, China |
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| Abstract: | 1,6-Methano 10] annulene-3,4-dicarboxylic anhydride (2) was prepared by a convenient synthesis starting from diethyl 1,6-methano 10] annulene-3,4-dicarboxylate (1) via saponification followed by acidification. A series of N-amino substituted 1,6-methano10] annulene-3,4-dicarboximides (3a-d) were synthesized by re-action of (2) with different primary amines (aniline, benzylamine, phenylethylamine, n-butylamine) in refluxing in acetic acid for 3 h, and the structures of the new compounds were determined by ~1H-NMR and ~(13)C-NMR spec-troscopy, mass spectrometry and high resolution mass spectrometry. |
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| Keywords: | 1 6-methanoannulene dicarboximide spectrum |
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