| 不同酸对界面聚合法合成聚邻甲苯胺结构和性能的影响 |
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| 引用本文： | 阿孜古丽·木尔赛力木,吐尔逊阿依·艾拜都拉,布阿依夏木·达吾提,粟智.不同酸对界面聚合法合成聚邻甲苯胺结构和性能的影响[J].内蒙古大学学报(自然科学版),2010,41(4). |
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| 作者姓名： | 阿孜古丽·木尔赛力木 吐尔逊阿依·艾拜都拉 布阿依夏木·达吾提 粟智 |
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| 作者单位： | 1. 新疆师范大学化学化工学院,乌鲁木齐 830054;新疆师范大学新能源材料化学实验室,乌鲁木齐 830054
2. 新疆师范大学化学化工学院,乌鲁木齐,830054 |
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| 基金项目： | 新疆高校科研计划重点资助项目，新疆师范大学优秀青年教师(自然科学类)科研启动基金 |
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| 摘 要： | 采用界面聚合法以邻甲苯胺为单体合成了硫酸、磷酸和醋酸掺杂态聚邻甲苯胺.通过红外光谱,粘度测定,X-射线粉末衍射,循环伏安,电导率测试等手段对质子酸掺杂聚邻甲苯胺进行了表征,讨论不同强度的酸对聚邻甲苯胺结构和性能的影响.结果表明,硫酸掺杂聚邻甲苯胺的分子量、结晶性、电化学活性和电导率最佳,而磷酸掺杂聚邻甲苯胺的各项性能最差.
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| 关 键 词： | 聚邻甲苯胺 界面聚合 酸掺杂 |
Influence of Different Acids on the Structure and Properties of Interfacial Synthesized Poly(o-toluidine) |
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| Arzugul·Muslim,Tursunay·Abay,Buayxam·Dawut,SU Zhi.Influence of Different Acids on the Structure and Properties of Interfacial Synthesized Poly(o-toluidine)[J].Acta Scientiarum Naturalium Universitatis Neimongol,2010,41(4). |
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| Authors: | Arzugul·Muslim Tursunay·Abay Buayxam·Dawut SU Zhi |
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| Institution: | Arzugul·Muslim1,2,Tursunay·Abay1,Buayxam·Dawut1,SU Zhi1,2(1.School of Chemistry and Chemical Engineering,Xinjiang Normal University,Urumqi 830054,China,2.Laboratory of New Energy Materials Chemistry,China) |
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| Abstract: | Poly(o-toluidine) doped with three different acids(sulfuric acid,phosphoric acid,acetic acid) were synthesized by using an interfacial synthesis method.The FT-IR,viscosity measurement,XRD,voltammetric studies and conductivity measurements were done to characterize the molecular structures,molecular weight,crystallinity and electrochemical behaviors of these polymers.The influence of different acids on the structure and properties of poly(o-toluidine) was discussed.The results showed that sulfuric acid doped... |
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| Keywords: | poly(o-toluidine) interfacial synthesis acid doping |
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