| 丙烯腈水相沉淀聚合机理及其动力学证据 |
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| 引用本文： | 陈忠仁,于在璋,李宝芳,潘祖仁.丙烯腈水相沉淀聚合机理及其动力学证据[J].北京工商大学学报(自然科学版),1991(1). |
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| 作者姓名： | 陈忠仁 于在璋 李宝芳 潘祖仁 |
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| 作者单位： | 北京轻工业学院化学工程系
(陈忠仁)，浙江大学化工系
(于在璋，李宝芳)，浙江大学化工系(潘祖仁) |
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| 摘 要： | 本文探讨了NaClO_3～Na_2SO_3-H~+引发AN-MA-SMAS水相沉淀聚合体系的引发机理、聚合场所、自加速现象、优先吸附等聚合机理问题,并通过端基分析、分子量及分布、表观竞聚率、种子聚合等有关研究,提出了相应的动力学证据.
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| 关 键 词： | 沉淀聚合 氧化还原体系 种子聚合 端基分析 表观竞聚率 |
KINETICS EVIDENCE FOR MECHANISMS OF PRECIPITATION COPOLYMERIZATION OF ACRYLONITRILE IN AQUEOUS MEDIUM WITH REDOX SYSTEM AS AN INITIATOR |
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| Chen Zhongren Beijing Institute of Light Industry
Yu Zaizhang,Li Baofang,Pan Zuren Zhejiang University.KINETICS EVIDENCE FOR MECHANISMS OF PRECIPITATION COPOLYMERIZATION OF ACRYLONITRILE IN AQUEOUS MEDIUM WITH REDOX SYSTEM AS AN INITIATOR[J].Journal of Beijing Technology and Business University:Natural Science Edition,1991(1). |
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| Authors: | Chen Zhongren Beijing Institute of Light Industry
Yu Zaizhang Li Baofang Pan Zuren Zhejiang University |
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| Institution: | Chen Zhongren Beijing Institute of Light Industry
Yu Zaizhang;Li Baofang;Pan Zuren Zhejiang University |
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| Abstract: | Initiation mechanism, polymerization loci, auto-acceleration, preferntial adsorption, and other mechanism-related problems have been discussed. End-group analysis, molecular weight distribution, apparent monomer reactivity ratio, seeded polymerization etc. have been investigated in order to provide kinetics evidence for reaction mechanisms of this polymerization system. |
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| Keywords: | precipitation polymerization redox system seeded polymerization end-group analysis apparent monomer reactivity ratio |
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