| 三维无机-有机杂化材料[Co(C_4H_4N_2)(VO_3)_2]_n的溶剂热法合成 |
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| 引用本文： | 白海丹,李增和.三维无机-有机杂化材料[Co(C_4H_4N_2)(VO_3)_2]_n的溶剂热法合成[J].北京工商大学学报(自然科学版),2007,25(5):12-16. |
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| 作者姓名： | 白海丹 李增和 |
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| 作者单位： | 1. 中国化工信息中心,北京,100029
2. 北京化工大学,理学院,北京,100029 |
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| 摘 要： | 以氯化钴、吡嗪和偏钒酸铵为原料,采用溶剂热法合成了一种三维网状无机-有机杂化材料Co(C4H4N2)(VO3)2]n.对影响溶剂热反应的主要因素如反应温度、pH值、反应溶剂等进行了系统研究,确定了合成该化合物的较佳反应条件.同时还研究了不同的有机桥式配体吡嗪、2-吡嗪羧酸、4,4′-联吡啶和1,2-联(4-吡啶基)乙烷在钴钒体系中的作用.
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| 关 键 词： | 无机-有机杂化材料 溶剂热法 配位结构 反应条件 |
| 文章编号： | 1671-1513（2007）05-0012-05 |
| 收稿时间： | 2007-04-03 |
| 修稿时间： | 2007年4月3日 |
SOLVOTHERMAL SYNTHESIS OF THREE-DIMENSIONAL INORGANIC-ORGANIC HYBRID MATERIALS [Co(C4H4N2)(VO3)2]n |
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| BAI Hai-dan,LI Zeng-he.SOLVOTHERMAL SYNTHESIS OF THREE-DIMENSIONAL INORGANIC-ORGANIC HYBRID MATERIALS [Co(C4H4N2)(VO3)2]n[J].Journal of Beijing Technology and Business University:Natural Science Edition,2007,25(5):12-16. |
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| Authors: | BAI Hai-dan LI Zeng-he |
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| Institution: | 1. China National Chemical Information Center, Beijing ;2. College of Science, Beijing University of Chemical Technology, 100029, China; Beijing 100029, China |
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| Abstract: | A novel inorganic-organic hybrid compoundCo(C4H4N2)(VO3)2]n was synthesized by solvothermal reaction.The reaction conditions such as reaction temperature,pH value and solvent were systematically investigated and the optimum conditions of this reaction were determined.The influences of different organic bridging ligands pyrazine,2-pyrazinecarboxylate,4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane on the cobalt vanadate system were explored. |
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| Keywords: | inorganic-organic hybrid materials solvothermal reaction coordination structure reaction condition |
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