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向日葵根分泌物对黄壤吸附Cd^2+行为的影响
引用本文:张道勇,潘响亮,黄承玲.向日葵根分泌物对黄壤吸附Cd^2+行为的影响[J].农业系统科学与综合研究,2009,25(4):406-409.
作者姓名:张道勇  潘响亮  黄承玲
作者单位:1. 中国科学院新疆生态与地理研究所,新疆,乌鲁木齐,830011;中国科学院地球化学研究所环境地球化学国家重点实验室,贵州,贵阳,550002
2. 贵州大学林学院,贵州,贵阳,550025
基金项目:中国科学院.百人计划"项目,中国科学院知识创新工程重要方向性项目,国家自然科学基金项目 
摘    要:从pH的影响、等温吸附、吸附动力学和热动力学4个方面研究了向日葵根分泌物对黄壤吸附Cd^2+的行为的影响。随着pH的升高,黄壤对Cd^2+的吸附量都升高,而且在pH为3~8的范围内,根分泌物的存在都减少了黄壤对Cd^2+的吸附。不论有否根分泌物存在,Langmuir方程和Freundlich方程能满意地描述黄壤对Cd^2+的等温吸附行为,黄壤对镉的吸附动力学符合拟二级速率方程,是一个墒减的放热的自发反应。向日葵根分泌物的存在抑制了黄壤对镉的吸附容量和吸附速率,并一定程度上降低了吸附过程的自发性。图4,表3,参11。

关 键 词:根分泌物    黄壤  吸附

Effects of Root Exudates from Helianthus annuus on Adsorption of Cd2+ on Yellow Earth
ZHANG Dao-yong,PAN Xiang-liang,HUANG Cheng-ling.Effects of Root Exudates from Helianthus annuus on Adsorption of Cd2+ on Yellow Earth[J].System Sciemces and Comprehensive Studies In Agriculture,2009,25(4):406-409.
Authors:ZHANG Dao-yong  PAN Xiang-liang  HUANG Cheng-ling
Institution:ZHANG Dao-yong, PAN Xiang-liang, HUANG Cheng-ling( 1. Xinjiang Institute of Ecology and Geography, Chinese Academy of Sciences, Urumuqi 830011, China; 2. State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China ; 3. Forestry College of Guizhou University, Guiyang 550025, China )
Abstract:The effects of root exudates from Helianthus annuus on Cd~(2+) adsorption to yellow earth were investigated in the present study. It was found that root exudates generally inhibited adsorption of Cd~(2+) onto yellow earth. Cd~(2+) adsorption capacity increased on increasing of solution pH and the presence of root exudates reduced Cd~(2+) adsorption capacity at pH 3 - 8-Cd~(2+) isothermal adsorption could be well represented with both Langmuir and Freundlich equations, and the adsorption kinetics with pseudo-second order equation. Cd~(2+) adsorption capacity to yellow earth is a spontaneous exothermic reaction.The presence of root exudates reduced the adsorption capacity and adsorption rate.
Keywords:root exudates  Cadmium  yellow earth  adsorption
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