| 电子垃圾污染地区生物样品中痕量多溴二苯醚的检测 |
| |
| 引用本文： | 梁淑轩,赵茜,杨中军.电子垃圾污染地区生物样品中痕量多溴二苯醚的检测[J].河北大学学报(自然科学版),2009,29(5):511. |
| |
| 作者姓名： | 梁淑轩 赵茜 杨中军 |
| |
| 作者单位： | 1.河北大学化学与环境科学学院,河北保定,071002； 2.南阳红宇机电有限公司,河南南阳,474675 |
| |
| 基金项目： | 国家自然科学基金重点资助项目 |
| |
| 摘 要： | 建立了气相色谱负化学电离质谱法(GC/NCI-MS)同时测定环境生物样品中一至十溴二苯醚中的42种同类物的方法.样品经过预处理后用双溶剂混合液提取,多层硅胶柱净化,浓缩后进行GC/NCI-MS测定.具有严格的质量控制和质量保证分析步骤,初始精密度实验和实验中的精密度实验的相对标准偏差(RSD)<15%,PBDEs的仪器检出限为0.22～1.99 pg.此方法测定标准参考物质WMF-01(鱼粉)中PB-DEs,得到了满意的结果,方法简便,净化效果好,费用低.将该方法应用于电子垃圾拆解地区的生物样品中华圆田螺和泽蛙中多溴二苯醚的实际检测,多溴二苯醚质量分数最高达到25 ng/g.
|
| 关 键 词： | 气相色谱负化学电离源质谱法 多溴二苯醚 同时测定 |
Quantification of Trace Polybrominated Diphenyl Ether in Biota Samples from an Electronic Waste Recycling Area |
| |
| LIANG Shu-xuan,ZHAO Qian,YANG Zhong-jun.Quantification of Trace Polybrominated Diphenyl Ether in Biota Samples from an Electronic Waste Recycling Area[J].Journal of Hebei University (Natural Science Edition),2009,29(5):511. |
| |
| Authors: | LIANG Shu-xuan ZHAO Qian YANG Zhong-jun |
| |
| Institution: | 1.College of Chemistry and Environmental Science;Hebei University;Baoding 071002;China;2.Nanyang Hongyu Machinery and Electronic Co.Ltd;Nanyang 474675;China |
| |
| Abstract: | A gas chromatography-negative chemical ionization mass spectrometry(GC/NCI-MS) method has been established for the analysis of environmental biota samples into forty-two congeners containing mono-to deca-brominated diphenyl ethers,respectively.The samples were extracted by mixed solvent,cleaned up with multi-layer silica gel column,and then analyzed by proposed GC/NCI-MS method.Method quality control and instrumental quality control were carried out.The relative standard deviation was lower than 15% for ini... |
| |
| Keywords: | gas chromatography-negative chemical ionization mass spectrometry polybrominated diphenyl ethers si multaneous detection |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《河北大学学报(自然科学版)》浏览原始摘要信息 |
| 点击此处可从《河北大学学报(自然科学版)》下载免费的PDF全文 |
