| 碱性介质中钯离子注铁电极上硝基苯的电化学行为 |
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| 引用本文： | 朱先军.碱性介质中钯离子注铁电极上硝基苯的电化学行为[J].咸宁学院学报,1995(3). |
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| 作者姓名： | 朱先军 |
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| 摘 要： | 本文研究了Ｆｅ及Ｐｄ／Ｆｅ电极在０．１ｍｏｌ／ＬＮａＯＨ溶液中的阴极极化行为，通过循环伏安法研究了硝基苯（ＮＢ）在Ｆｅ及Ｐｄ／Ｆｅ电极上的电化学行为，ＮＢ在注钯剂量较大的Ｐｄ／Ｆｅ电极上还原效果较好，最后提出了碱性溶液中ＮＢ在Ｐｄ／Ｆｅ电极上电还原的机理．
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| 关 键 词： | 离子注入 钯 铁 硝基苯 |
The Behavior of Nitrobenzene Electrochemical Reduction on Palladium Implanted Iron |
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| Zhu Xianjun.The Behavior of Nitrobenzene Electrochemical Reduction on Palladium Implanted Iron[J].Journal of Xianning College,1995(3). |
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| Authors: | Zhu Xianjun |
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| Institution: | Zhu Xianjun |
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| Abstract: | By using cyclic voltammetry, Nitrobenzene electrochemical reduction in 0.1 mol/ L NaOH solutions was investigated, Pd/Fe electrodes is superior to Fe electrode, the higher the Pd dose in Pd/Fe, the more the effection, in the end we try to explain the electroreduction mechanism of NB in basic aqueos solution, on Fe the radical anion of NB to phenylhydroxylamine would Proceed by EP mechanism, on Pd/Fe the radical anion of NB to phenylhydroxylamine would proceed by ECH mechanism. |
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| Keywords: | Ion Implantation Palladium Iron Nitrobenzene |
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