| 苦皮素A的化学结构讨论 |
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| 引用本文： | 赵天增,张海艳,魏悦,李倩,张城达.苦皮素A的化学结构讨论[J].河南科学,2011,29(10):1168-1171. |
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| 作者姓名： | 赵天增 张海艳 魏悦 李倩 张城达 |
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| 作者单位： | 1. 河南省科学院天然产物重点实验室,郑州,450002
2. 河南工业大学化工学院,郑州,450052 |
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| 基金项目： | 河南省省院科技合作项目(102106000026) |
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| 摘 要： | 对苦皮素A进行了1H和13C MNR检测,通过DEPT和1H-1H COSY、HSQC、HMBC等2 D NMR技术对该化合物所有的1H和13C NMR信号进行了全归属和详细解析,并采用HMBC技术对文献中与苦皮素A化学结构相关的错误报道进行了修正.
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| 关 键 词： | NMR 归属 2 D NMR HMBC 苦皮素 A |
A Study on Angulatin A |
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| Zhao Tianzeng,Zhang Haiyan,Wei Yue,Li Qian,Zhang Chengda.A Study on Angulatin A[J].Henan Science,2011,29(10):1168-1171. |
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| Authors: | Zhao Tianzeng Zhang Haiyan Wei Yue Li Qian Zhang Chengda |
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| Institution: | Zhao Tianzeng 1,Zhang Haiyan 1,Wei Yue 1,Li Qian 1,Zhang Chengda 2 (1.Key Laboratory of Natural Products,Henan Academy of Science,Zhengzhou 450002,China,2.College of Chemical Engineering,Henan University of Technology,Zhengzhou 450052,China) |
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| Abstract: | One insecticidal active compound,angulatin A,was isolated from an insecticidal plant,Celastrus Angu-latus Maxim.In this paper,using a combination of 1 D(1 H,13 C NMR,NOE and DEPT)and 2 D NMR(1 H-1 H COSY,HSQC,HMBC and NOESY) techniques,its 1 H and 13 C NMR spectras was completely assigned and analyzed.Its structure in the literature was corrected by HMBC technique. |
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| Keywords: | NMR assignment 2 DNMR HMBC angulatin A |
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