| 含有大的吸电子取代基的主族元素新化合物的合成 |
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| 引用本文： | 薛宝玉,赵俊宏,樊燕鸽,李文锋,KeithB.Dillon.含有大的吸电子取代基的主族元素新化合物的合成[J].河南科学,2011,29(8):907-909. |
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| 作者姓名： | 薛宝玉 赵俊宏 樊燕鸽 李文锋 KeithB.Dillon |
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| 作者单位： | 1. 河南省科学院化学研究所,郑州,450002
2. Chemistry Department, University of Durham, Durham DH1 3LE, UK |
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| 摘 要： | 通过四氯化物ECl4(E是Si,Ge,Sn或As)和三氯化砷AsCl3分别与ArLi,Ar' Li或Ar"Li反应首先合成了10种新的主族元素化合物R1-2ECl1-2,其中R是2,4,6- (CF3) 3C6H2 (Ar),2,6- (CF3)2C6H3 (Ar')或2,4- (CF3) 3C6h3 (Ar")；Ar...
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| 关 键 词： | 主族元素化合物 吸电子取代基 元素分析 |
Synthesis of New Main Group Element Compounds with Bulky Electron-Withdrawing Substituents |
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| Xue Baoyu,Zhao Junhong,Fan Yange,Li Wenfeng,KeithB.Dillon.Synthesis of New Main Group Element Compounds with Bulky Electron-Withdrawing Substituents[J].Henan Science,2011,29(8):907-909. |
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| Authors: | Xue Baoyu Zhao Junhong Fan Yange Li Wenfeng KeithBDillon |
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| Institution: | Xue Baoyu1,Zhao Junhong1,Fan Yange1,Li Wenfeng1,Keith B. Dillon2(1. Institute of Chemistry,Henan Academy of Sciences,Zhengzhou 450002,China,2. Chemistry Department,University of Durham,Durham DH1 3LE,UK) |
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| Abstract: | Some new main group element compounds R1-2ECl1-2 E=Si,Ge,Sn or As; R=2,4,6-(CF3) 3C6H2 (Ar),2,6-(CF3) 2C6H3 (Ar') or 2,4- (CF3) 3C6H3 (Ar"),Ar,Ar' and Ar" are all bulky and highly electron-withdrawing substituents ]were first synthesized by reactions of ECl(3-4) with ArLi,Ar' Li or Ar"Li.The products were characterized by elemental analysis. |
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| Keywords: | main group element compound electron-withdrawing substituent elemental analysis Biography |
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