| 5-(4-对氯苯基)-10,15,20-三苯基卟啉及其配合物的催化性质研究 |
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| 引用本文： | 贾密英,王静秋.5-(4-对氯苯基)-10,15,20-三苯基卟啉及其配合物的催化性质研究[J].河北师范大学学报(自然科学版),1997(3). |
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| 作者姓名： | 贾密英 王静秋 |
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| 作者单位： | 河北师范大学化学系(贾密英)，武汉大学化学系(王静秋) |
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| 摘 要： | 对金属卟啉催化性质的研究愈来愈引起人们的关注，尤其是与分子氧有关的催化反应〔１〕．该文研究了标题卟啉（Ｈ２Ｐ）及其６种配合物存在下，用分子氧氧化芳醛的催化过程，测定了反应体系的吸氧动力学曲线
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| 关 键 词： | 金属卟啉 催化氧化 |
Studies on Catalytic Porperties of 5(4ChloroPhenyl) -10,15,20Triphenylporphyrin and its Complexes |
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| Jia Miying,Wang Jingqiu.Studies on Catalytic Porperties of 5(4ChloroPhenyl) -10,15,20Triphenylporphyrin and its Complexes[J].Journal of Hebei Normal University,1997(3). |
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| Authors: | Jia Miying Wang Jingqiu |
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| Institution: | Jia Miying 1) Wang Jingqiu 2) |
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| Abstract: | The oxidation of aromatic aldehydes with O 2 has been investigated in the presence of MP(Cl)(M=Fe,Co,Ni,Mn,Cu and Zn).The oxygen uptake volume of MP(Cl)during the course of the reaction was measured.It was observed three complexes M APCl(M A=Fe,Mn,Co)can catalyze the oxidation of aromatic aldehydes,while H 2P and other complexes M BP (M B=Ni,Cu and Zn)are inactive.On the other hand it was studied that the effect of substrates on oxidation of aromatic aldehydes. |
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| Keywords: | metalloporphyrin catalytic oxidation |
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