| 直接缩聚法合成淀粉接枝可降解聚酯和聚酯酰胺及其表征 |
| |
| 引用本文： | 路德待,王寿峰,任宗礼,张小伟,雷自强.直接缩聚法合成淀粉接枝可降解聚酯和聚酯酰胺及其表征[J].中山大学学报(自然科学版),2007,46(Z1). |
| |
| 作者姓名： | 路德待 王寿峰 任宗礼 张小伟 雷自强 |
| |
| 作者单位： | 甘肃省高分子材料重点实验室∥西北师范大学化学化工学院 甘肃兰州730070 |
| |
| 摘 要： | 以可溶性淀粉、乳酸、乙醇酸和己内酰胺为原料在氯化亚锡催化下直接缩聚制备得到了淀粉接枝乳酸-乙醇酸共聚物及淀粉接枝乳酸-乙醇酸-己内酰胺共聚物。用核磁共振(NMR)、差热(DSC)及热重(TG)分析分别对产物的结构和热性能进行了表征。
|
| 关 键 词： | 生物可降解 淀粉 接枝 直接缩聚 |
Synthesis and Characterization of Starch Grafted Biodegradable Polyester and Polyesteramide by Direct Polycondensation |
| |
| LU De-dai,WANG Shou-feng,REN Zong-li,ZHANG Xiao-wei,LEI Zi-qiang.Synthesis and Characterization of Starch Grafted Biodegradable Polyester and Polyesteramide by Direct Polycondensation[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2007,46(Z1). |
| |
| Authors: | LU De-dai WANG Shou-feng REN Zong-li ZHANG Xiao-wei LEI Zi-qiang |
| |
| Abstract: | Copolymers of starch grafted with poly(lactic-co-glycolic acid) and poly(lactic-co-glycolic acid-co-caprolactam) were prepared by direct polycondensation of soluble starch with lactic acid, glycolic acid and caprolactam in the presence of stannous chloride SnCl2]. The chemical microstructure of the resultant grafted copolymers was clarified by NMR spectroscopy and the thermal properties was investigated by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis. |
| |
| Keywords: | Biodegradable Starch graft Direct polycondensation |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
