| Ni（mpz）_4X_2（X＝Cl，Br，I）型化合物光磁性质的理论研究 |
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| 引用本文： | 杨复兴,颜占先,鲁帮德,蒋光和. Ni（mpz）_4X_2（X＝Cl，Br，I）型化合物光磁性质的理论研究[J]. 湖南师范大学自然科学学报, 1996, 0(2) |
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| 作者姓名： | 杨复兴 颜占先 鲁帮德 蒋光和 |
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| 作者单位： | 吉首大学物理系 |
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| 摘 要： | 利用ｄ８（Ｄ４ｈ＊）全组态混合统一晶场理论对Ｎｉ（ｍｐｚ）４Ｘ２型化合物光谱、零场分袭（ＺＦＳ）、（ＤＰＲ）参量、顺磁磁化率进行了统一的理论计算，理论结果与实验观测值吻合较好．因此对该化合物的光、磁性质作出了完全统一的理论解释．
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| 关 键 词： | Ni（mpz）_2X_2型化合物；光谱；顺磁磁化率；D_（2h）点群对称性 |
Theoretical Research on Optical and Magnetic Properties of The Ni(mpz)_4I_2 (X=Cl, Br,I) Compounds |
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| Yang Fuxing,Yan ZhanxianLu Bangde,Jiang Guanghe. Theoretical Research on Optical and Magnetic Properties of The Ni(mpz)_4I_2 (X=Cl, Br,I) Compounds[J]. Journal of Natural Science of Hunan Normal University, 1996, 0(2) |
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| Authors: | Yang Fuxing Yan ZhanxianLu Bangde Jiang Guanghe |
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| Abstract: | By means of complete configuration mixing unified theory for d2,3(D*2h),the optical absorption spectrum,the ground state zero-field spliting parameters,the EPR parameters and the magnetic susceptility of the compounds Ni (mpz)4X2 have been calculated theortically and uniformly.This results agree with the experimental values basically, therefore we explained the optical and magnetic properties of the compounds the oretically and completely uniformly. |
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| Keywords: | Ni(mpz)_4X_2 compounds spectrum susceptibility D_(2h) point group symmetry |
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