| 聚（N—甲基）苯胺作为蓄电池阴极活性材料的电化学性能研究 |
| |
| 引用本文： | 孙东豪.聚（N—甲基）苯胺作为蓄电池阴极活性材料的电化学性能研究[J].苏州大学学报(医学版),1998,14(2):79-83. |
| |
| 作者姓名： | 孙东豪 |
| |
| 作者单位： | 苏州大学丝绸学院 苏州 |
| |
| 摘 要： | 聚（Ｎ－甲基）苯胺作为一种新的二次电池阴极材料在酸性溶液中有很高的稳定性，由聚（Ｎ－甲基）苯胺膜电极Ｚｎ片，１．０ｍｏｌ／Ｌ，ＺｎＣｌ２水溶液（ｐＨ＝２．０１）构成的电池，其开路电压的１．３１Ｖ，在恒电流放电速率为０．１５ｍＡ／ｃｍ＾２（放电电压为０．９Ｖ，聚合物重量为２．０ｍｇ／ｃｍ＾２）聚（Ｎ－甲基）苯胺的容量密度和能量密度分别为９７．５Ａｈ／ｋｇ，９４．６Ｗｈ／ｋｇ，在上述充放电电流密度下，
|
| 关 键 词： | 电化学性质 聚苯胺 蓄电池 阴极活性材料 |
STUDY OF THE ELECTROCHEMICAL PROPERTIES OF POLY-N-METHYLANILINE USED AS A CATHODE-ACTIVE MATERIAL IN RECHARGEABLE BATTERIES |
| |
| Sun Donghao.STUDY OF THE ELECTROCHEMICAL PROPERTIES OF POLY-N-METHYLANILINE USED AS A CATHODE-ACTIVE MATERIAL IN RECHARGEABLE BATTERIES[J].Journal of Suzhou University(Natural Science),1998,14(2):79-83. |
| |
| Authors: | Sun Donghao |
| |
| Abstract: | A nwe conductive polymer,poly-N-methylaniline,used as acathode -active material in rechargeable batteries,is very stable in aqueous solution. The cell, composed of poly-N-methylaniline, Zn and 1. 0 mol/L ZnCl2(pH = 2. 01), hah an open - circuit voltage of 1. 31V. The capacity value and energy density of poly-N-methylaniline are 97. 5Ah/kg and 94. 6 Wh/kg at a constant discharge current of 0. 15 mA/cm2 (discharge voltage 0. 90V, the weight of polymer;35. 6 mg/cm2). The coulombic efficiency of poly-N-methylaniline is 95. 4.% at a constant current rate of 0. 15 mA/cm2. |
| |
| Keywords: | Poly-N-methylaniline Electrode material Alectrochemical property |
| 本文献已被 CNKI 维普 等数据库收录！ |
