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纳米多晶TiO2的光催化性能
引用本文:祝红丽,陈克复,漆德威,杨仁党.纳米多晶TiO2的光催化性能[J].华南理工大学学报(自然科学版),2009,37(3).
作者姓名:祝红丽  陈克复  漆德威  杨仁党
作者单位:1. 华南理工大学,制浆造纸工程国家重点实验室,广东,广州,510640
2. 西密歇根大学,工程与应用科学学院,美国,密歇根州,49008
基金项目:广东省自然科学基金,华南理工大学制浆造纸工程国家重点实验室开放式基金
摘    要:以纯锐钛矿型和纯金红石型TiO2为原料,通过超声分散制备复合晶态的TiO2,研究纳米TiO2的晶相组成对光催化性能的影响.通过X射线衍射分析表征晶相组成与晶粒尺寸;以甲苯为目标降解物,采用气相色谱检测复合晶态的TiO2对甲苯的降解效果.结果表明:锐钛矿型TiO2的光催化性能明显地优于金红石型TiO2,但由于协同作用,一定比例的金红石能提高纳米多晶TiO2的光催化性能;当晶相中锐钛矿型与金红石型TiO2的质量比为83∶17时,纳米多晶TiO2具有最佳光催化活性.

关 键 词:纳米二氧化钛  晶相组成  光催化性能

Photocatalytic Activity of Nano-Polycrystalline Titania
Zhu Hong-li,Chen Ke-fu,Qi De-wei,Yang Ren-dang.Photocatalytic Activity of Nano-Polycrystalline Titania[J].Journal of South China University of Technology(Natural Science Edition),2009,37(3).
Authors:Zhu Hong-li  Chen Ke-fu  Qi De-wei  Yang Ren-dang
Institution:Zhu Hong-li1 Chen Ke-fu1 Qi De-wei2 Yang Ren-dang1(1.State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China,2.College of Engineering and Applied Science,Western Michigan University,Michigan 49008,USA)
Abstract:Polycrystalline TiO2 was prepared by means of ultrasonic dispersion,with pure anatase and rutile as the raw materials.The effect of crystal phase composition on the photocatalytic activity of the nano-polycrystalline TiO2 was then investigated.In the investigation,XRD was employed to analyze the crystal phase composition and crystal size,and gas chromatography was employed to evaluate the toluene degradation photo-assisted by the nano-polycrystalline TiO2.Experimental results show that,although the photocat...
Keywords:nano-sized titania  crystal phase composition  photocatalytic activity  
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