| 普鲁士蓝-六氰亚铁酸镍膜修饰铂电极的现场FTIR光谱电化学 |
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| 引用本文： | 林祥钦,薄爱丽.普鲁士蓝-六氰亚铁酸镍膜修饰铂电极的现场FTIR光谱电化学[J].安徽师范大学学报(自然科学版),1999,22(1):1-4. |
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| 作者姓名： | 林祥钦 薄爱丽 |
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| 作者单位： | 1. 中国科学技术大学化学系,安徽,合肥,230026
2. 长春应用化学研究所电分析开放实验室,国家电化学和光谱分析测试中心,吉林,长春,130022 |
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| 摘 要： | 报道电化学方法制备的普鲁士蓝│铂修饰电极（ＰＢ│Ｐｔ）和ＰＢ－六氰亚铁酸镍混合物膜│铂修饰电极（ＰＢ－ＮｉＨＣＦ│Ｐｔ）的循环状安和现场付立叶红外光谱电化学研究，发现不论ＰＢ膜还是ＰＢ－ＮＣＦ混合物膜经过脱水处理后，两膜中中ＰＢ的电化学还原反应受到了显著的抑制，而对ＮＣＦＣＦ结构的影响较小。
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| 关 键 词： | 普鲁士蓝 六氰亚铁酸镍 现场付立叶红外光谱电化学 循环伏安 修饰电极 |
ELECTROCHEMICAL AND IN-SITU FTIR SPECTROELECTROCHEMICAL STUDY ON PLUSSIAN BLUE(PB) AND PB-NiHCF MIXURAL FILM MODIFIED PLATINUM ELECTRODE |
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| LIN Xiang-qin,BO Ai-li.ELECTROCHEMICAL AND IN-SITU FTIR SPECTROELECTROCHEMICAL STUDY ON PLUSSIAN BLUE(PB) AND PB-NiHCF MIXURAL FILM MODIFIED PLATINUM ELECTRODE[J].Journal of Anhui Normal University(Natural Science Edition),1999,22(1):1-4. |
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| Authors: | LIN Xiang-qin BO Ai-li |
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| Abstract: | The paper reports the cyclic voltammetry and in situ FTIR spectroelectrochemistry of electrochemically prepared prussian blue and prussian blue-nickel hexacyanoferrate mixtue modified platinum electrodes (PB|Pt and PB NiHCF|Pt). It is found that the reduction rections of PB structure on these two films can be significanty inhibited, however less effect to the NiHCF structure. |
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| Keywords: | prussian blue nickel hexacyanoferrate in situ FTIR spectroelectrochemistry cyclic voltammetry modified electrode |
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