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光电功能型超分子聚合物的研究进展
引用本文:赵剑锋,林进义,石乃恩,解令海,黄维. 光电功能型超分子聚合物的研究进展[J]. 南京邮电大学学报(自然科学版), 2012, 32(4): 83-90
作者姓名:赵剑锋  林进义  石乃恩  解令海  黄维
作者单位:南京邮电大学信息材料与纳米技术研究院,江苏南京210046;南京邮电大学有机电子与信息显示国家重点实验室培育基地,江苏南京210046
基金项目:国家重点基础研究发展计划(973计划)(2009CB930600);国家自然科学基金(20704023,60876010,60706017,20774043);教育部重点项目(208050,707032);江苏省高校自然科学基础研究项目(BK2008053,SJ209003,TJ209035,TJ207035)资助项目
摘    要:超分子聚合物是重复单元经超分子弱键作用链接而形成的聚集体,是功能软物质中一种新的组织方式。文中基于众多超分子聚合物的分类,重点论述主链式光电功能型超分子聚合物(optoelectronic supramolecular poly-mer,OSP)在太阳能电池、有机电致光、电致变色等得到深入研究领域的应用进展;通过调控能量转移、电荷转移、载流子迁移率等可以实现OSP的白光、光电转换、电致变色等性质和相关器件,并使OSP日渐成为超分子化学与有机电子等学科交叉领域研究的新热点;最后展望了OSP的研究趋势。

关 键 词:超分子聚合物  有机半导体  非共价键作用  自组装

Research Progress in Optoelectronic Supramolecular Polymers
ZHAO Jian-feng , LIN Jin-yi , SHI Nai-en , XIE Ling-hai , HUANG Wei. Research Progress in Optoelectronic Supramolecular Polymers[J]. JJournal of Nanjing University of Posts and Telecommunications, 2012, 32(4): 83-90
Authors:ZHAO Jian-feng    LIN Jin-yi    SHI Nai-en    XIE Ling-hai    HUANG Wei
Affiliation:1,2 1.Institute of Advanced Materials,Nanjing University of Posts and Telecommunications,Nanjing 210046,China 2.Key Laboratory for Organic Electronics & Information Displays(KLOEID),Nanjing University of Posts and Telecommunications,Nanjing 210046,China
Abstract:Supramolecular polymer,the aggregates of repeated monomers bonded by supramolecular weak interactions,is one of the new organizing forms of soft matters.This article mainly reviewed the research and application of main chain optoelectronic supramolecular polymers(OSP) on the basis of various reported supramolecular polymers,especially in solar cells,organic electroluminescene diodes,and electrochromic displays,etc.Properties of white luminescence,photo-electric conversion,and electrochromism can be realized by adjusting the energy transfer,charge transfer,and charge mobility properties of OSP.It has become a hot topic in the intercrossing fields of supramolecular chemistry and organic electronics.Finally,a perspective for future trend of OSP is proposed.
Keywords:supramolecular polymer  organosemiconductor  noncovalent interaction  self-assembly
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